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ChemicalBook CAS DataBase List 7-Methoxy-1H-indole
3189-22-8

7-Methoxy-1H-indole synthesis

10synthesis methods
-

Yield:-

Steps:

Multi-step reaction with 6 steps
1: SOCl2 / 2 h / 20 °C
2: 99 percent / bis(pyridine)iodonium(I) tetrafluoroborate; CF3SO3H / CH2Cl2 / 16 h / 20 °C
3: 90 percent / Et3N / Pd(PPh3)2Cl2-CuI / 3 h / 0 - 20 °C
4: 69 percent / CuI / dimethylformamide / 2.5 h / 100 °C
5: 95 percent / KOH; H2O / ethanol / 24 h / Heating
6: 65 percent / Cu2O / quinoline / 4 h / 230 °C

References:

Ezquerra, Jesus;Pedregal, Concepcion;Lamas, Carlos;Barluenga, Jose;Perez, Marta;Garcia-Martin, Miguel Angel;Gonzalez, Jose M. [Journal of Organic Chemistry,1996,vol. 61,# 17,p. 5804 - 5812]

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