ChemicalBook CAS DataBase List 6-Methoxy-2-Acetyl Naphthalene

6-Methoxy-2-Acetyl Naphthalene synthesis

13synthesis methods

Product Name:6-Methoxy-2-Acetyl Naphthalene
CAS Number:2700-47-2
Molecular formula:C14H14O2
Molecular Weight:214.26

93-04-9 Synthesis

93-04-9
462 suppliers
$13.00/25g

79-05-0 Synthesis

79-05-0
218 suppliers
$6.00/25g

2700-47-2
130 suppliers
$5.00/250mg

Yield: 85%

Reaction Conditions:

with triethylamine;tin(ll) chloride at 5 - 19; for 32.3333 h;Concentration;Temperature;

Steps:

3 Example 3
In the is provided with an agitator, reflux condenser, thermometer, dropping funnel in the reaction container, adding triethylamine to 310 ml, stannous chloride 0.65mol, control the stirring speed 190rpm, reducing the temperature of the solution to 5 °C, β-naphthyl methyl ether is slowly added (2) 0.65mol, adds by drops third amide (3) 0.47mol, dropping time control, in 80 min, maintaining the temperature of the solution reaction 9h, raising the temperature of the solution to 19 °C, standing 22h, the reactants are poured into the 1.8L the mass fraction of 25% sodium bisulfite solution, control the temperature of the solution in the 5 °C, steam distillation, until completely distilled until the triethylamine, control the stirring speed 130rpm, let solution of natural cooling, solidifying oily substance, filtering, potassium nitrate solution, anhydrous calcium sulfate dehydration, in the mass fraction is 92% recrystallized in cyclohexane solution, to get the yellow solid 6-methoxy-2-c acyl-naphthaline 85.49g, yield 85%.

References:

Chengdu Cardiff Technology Co., Ltd.;Liao, Ruer CN105439833, 2016, A Location in patent:Paragraph 0015; 0016