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220943-23-7

5-FLUORO-1H-INDOLE-2-CARBALDEHYDE synthesis

6synthesis methods
-

Yield:220943-23-7 84%

Reaction Conditions:

with manganese(IV) oxide in N,N-dimethyl-formamide at 20; for 12 h;Inert atmosphere;

Steps:

4.3. General procedure for the synthesis of indole-2-carbaldehyde(13a-13q)

General procedure: A suspension of the alcohol 12 (1 mmol) and active MnO2(10 mmol) in DMF (30 mL) was stirred at rt for 12 h. The reactionmixture was filtrated through a Celite pad. The filtrate was evaporatedin vacuo. The residue was purified by column chromatographyusing EtOAc-hexane as an eluent to give the indole-2-carbaldehyde 13.

References:

Nishiyama, Takashi;Hatae, Noriyuki;Yoshimura, Teruki;Takaki, Sawa;Abe, Takumi;Ishikura, Minoru;Hibino, Satoshi;Choshi, Tominari [European Journal of Medicinal Chemistry,2016,vol. 121,p. 561 - 577]

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