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ChemicalBook CAS DataBase List 4-(ETHYLTHIO)BENZENEBORONIC ACID
145349-76-4

4-(ETHYLTHIO)BENZENEBORONIC ACID synthesis

2synthesis methods
-

Yield:-

Steps:

Multi-step reaction with 2 steps
1.1: 94 percent / NaOH / tetrahydrofuran; H2O / 1 h / 100 °C
2.1: n-BuLi / tetrahydrofuran / 2 h / -78 °C
2.2: B(OMe)3 / tetrahydrofuran / -78 - 20 °C
2.3: 66 percent / 20percent HCl

References:

Percec;Bera;De Binod;Sanai;Smith;Holerca;Barboiu;Grubbs;Frechet [Journal of Organic Chemistry,2001,vol. 66,# 6,p. 2104 - 2117]

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