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588-20-5

(4-CHLORO-3-METHYL-PHENOXY)-ACETIC ACID synthesis

5synthesis methods
-

Yield:588-20-5 77%

Reaction Conditions:

with sodium hydroxide in ethanol;water;Reflux;

Steps:

3 4.1.2.1 General synthetic procedure for phenoxyacetic acid analogues (4a-j)

General procedure: Compounds (3a-j,0.02mol) were dissolved in ethanol (15mL), sodium hydroxide (0.035mol) in water (5mL) was added, and the mixture was refluxed for 5-9h. The reaction mixture was cooled and acidified with 2N hydrochloric acid. The precipitate was filtered, washed with water, and finally recrystallized from methanol to afford desired compounds (4a-j). Compound (4a) is takenas a representative example to explain physical and characterization data.

References:

Mohammed, Yasser Hussein Eissa;Malojirao, Vikas H.;Thirusangu, Prabhu;Al-Ghorbani, Mohammed;Prabhakar;Khanum, Shaukath Ara [European Journal of Medicinal Chemistry,2018,vol. 143,p. 1826 - 1839]

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