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ChemicalBook CAS DataBase List 3-Chloro-6-hydrazinopyridazine
17284-97-8

3-Chloro-6-hydrazinopyridazine synthesis

3synthesis methods
-

Yield:17284-97-8 100%

Reaction Conditions:

with hydrazine hydrate at 80; for 5 h;Sealed tube;

Steps:

L

Intermediate L6-((6-Chloro-[1 ,2,4]triazolo[4,3-b]pyridazin-3-yl)methyl)quinoline Acetic acid, 500C 3-Chloro-6-hydrazinylpyridazine (i) A mixture of 3,6-dichloropyridazine (3 g, 20.14 mmol) and hydrazine monohydride(1 g, 20.14 mmol) was heated in a sealed tube to 80 0C for 5 hours. Solvent was evaporated and the crude was used in the next step without purification (3.56 g, 100%). LCMS (method B): [MH]+ = 145.1 , tR = 0.57 min.

References:

WO2011/18454,2011,A1 Location in patent:Page/Page column 62-63

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