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ChemicalBook CAS DataBase List 2-Trifluoromethoxyphenol
32858-93-8

2-Trifluoromethoxyphenol synthesis

1synthesis methods
-

Yield:32858-93-8 88%

Reaction Conditions:

Stage #1:1-trifluoromethoxybenzene with N,N,N,N,-tetramethylethylenediamine;sec.-butyllithium in tetrahydrofuran;cyclohexane at -75; for 2 h;
Stage #2: with fluorodimethoxyborane diethyl etherate in tetrahydrofuran;cyclohexane at -75;
Stage #3: with sodium hydroxide;dihydrogen peroxide in tetrahydrofuran;cyclohexaneFurther stages.;

References:

Castagnetti, Eva;Schlosser, Manfred [European Journal of Organic Chemistry,2001,# 4,p. 691 - 695]

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