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ChemicalBook CAS DataBase List 2-Fluorobenzyl bromide
446-48-0

2-Fluorobenzyl bromide synthesis

3synthesis methods
-

Yield:-

Reaction Conditions:

with phosphorus tribromide in diethyl ether at 0; for 0.5 h;

Steps:

2.4. Synthesis of alkyl bromides (3a-l)

General procedure: To a solution of aryl alcohol (2a-l) (1 g) in ether (10 mL) was added phosphorus tribromide (0.5 equiv) and stirred for 0.5 h at 0 °C. After completion of reaction, excess phosphorus tribromide was quenched by adding sodium carbonate solution and then the residue was dissolved in EtOAc (100 mL) and washed with water (2 ×100 mL). The product containing organic layer was dried over anhydrous sodium sulfate and the product was purified by passing through a column chromatography.

References:

Battu, Satyanarayana;Joolakanti, Hima Bindhu;Kamepalli, Ramanjaneyulu;Miryala, Jeevanreddy [Journal of Molecular Structure,2021,vol. 1242]

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