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ChemicalBook CAS DataBase List 1H-Pyrrolo[3,2-b]pyridine-5-methanamine(9CI)
267876-26-6

1H-Pyrrolo[3,2-b]pyridine-5-methanamine(9CI) synthesis

4synthesis methods
65169-58-6 Synthesis
6-Cyano-2-methyl-3-nitropyridine

65169-58-6
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4637-24-5 Synthesis
N,N-Dimethylformamide dimethyl acetal

4637-24-5
607 suppliers
$5.00/25g

1H-Pyrrolo[3,2-b]pyridine-5-methanamine(9CI)

267876-26-6
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Yield:-

Reaction Conditions:

Stage #1: 6-methyl-5-nitropyridine-2-carbonitrile;N,N-dimethyl-formamide dimethyl acetal in N,N-dimethyl-formamide at 90; for 2 h;
Stage #2: with hydrogenchloride;methanol;palladium on activated charcoal for 16 h;

References:

Sanderson, Philip E. J.;Stanton, Matthew G.;Dorsey, Bruce D.;Lyle, Terry A.;McDonough, Colleen;Sanders, William M.;Savage, Kelly L.;Naylor-Olsen, Adel M.;Krueger, Julie A.;Lewis, S. Dale;Lucas, Bobby J.;Lynch, Joseph J.;Yan, Youwei [Bioorganic and Medicinal Chemistry Letters,2003,vol. 13,# 5,p. 795 - 798]

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