ChemicalBook CAS DataBase List 1-Nitro-3-oxiranylbenzene

1-Nitro-3-oxiranylbenzene synthesis

11synthesis methods

Product Name:1-Nitro-3-oxiranylbenzene
CAS Number:20697-05-6
Molecular formula:C8H7NO3
Molecular Weight:165.15

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Yield:20697-05-6 93%

Reaction Conditions:

with dihydrogen peroxide;N,N-dimethyl-formamide in water at 100; for 2 h;Green chemistry;

Steps:

General procedure: Styrene (0.10 g, 1.00 mmol) was added to a round-bottomedflask containing colloidal of Pd(II)AEA-Fe3O4NP(0.1 g) and DMA (0.02 mmol) in H2O (5 mL) and temperatureraise up to 100 °C. H2O2 (3 mmol) was addeddropwise to the reaction vessel during 0.5 h. After 1.5 h,the reaction mixture was cooled to room temperature, andPd(II)AEA-Fe3O4NP was separated by a magnet andwashed with acetone (2 × 5 mL). The filtrate solvent wasevaporated under vacuum, and the product purified withcolumn chromatography with n-hexane/ethylacetate (5:1).

References:

Keshipour, Sajjad;Khalteh, Nastaran Kalam [Journal of the Iranian Chemical Society,2016,vol. 13,# 11,p. 1977 - 1982]

2227-64-7 Synthesis