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ChemicalBook CAS DataBase List 1-(4-Methoxy-benzyl)-1H-pyrazole-4-carbaldehyde
153687-35-5

1-(4-Methoxy-benzyl)-1H-pyrazole-4-carbaldehyde synthesis

3synthesis methods
-

Yield:153687-35-5 93.3%

Reaction Conditions:

with potassium carbonate in acetonitrile; for 1 h;Reflux;

Steps:

32.1 Synthesis of 1-(4-methoxybenzyl)-1H-pyrazole-4-carbaldehyde

To a mixture of 1H-pyrazole-4-carbaldehyde (100 mg, 1.04 mmol) and 1- (chloromethyl)-4-methoxybenzene (162 mg, 1.04 mmol) in CH3CN (6 mL) was added potassium carbonate (287 mg, 2.08 mmol), the resulting mixture was stirred at reflux for 1 h. The mixture was poured into water (20 mL) and extracted with EtOAc (3×20 mL). The organic layer was dried over Na2SO4and concentrated to give 1-(4-methoxybenzyl)- 1H-pyrazole-4-carbaldehyde (220 mg, 93.3 %) as a colorless oil

References:

KR2017/45749,2017,A Location in patent:Paragraph 1087; 1090-1092