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ChemicalBook CAS DataBase List 1,4,5,8-Naphthalenetetracarboxylic dianhydride
81-30-1

1,4,5,8-Naphthalenetetracarboxylic dianhydride synthesis

14synthesis methods
-

Yield:81-30-1 73 g

Reaction Conditions:

in N,N-dimethyl acetamide;toluene at 111; for 2 h;Inert atmosphere;Solvent;Temperature;

Steps:

6

Into a 1000 mL three-neck flask were added 100.0 g of a composition containing 1,4,5,8-naphthalenetetracarboxylic acid and 1,4,5,8-naphthalenetetracarboxylic acid monoanhydride with a mass ratio of 86:14 and the solvent made up of 200 mL of N,N-dimethylacetamide and 400 mL of toluene at room temperature in a nitrogen flow. After being heated up to 111° C., the materials in the flask were subjected to a reaction with stirring at that temperature for 2 hours. The flask was cooled to 10° C., and the sample was stirred for 1 hour and then filtered to yield 73 g of 1,4,5,8-naphthalenetetracarboxylic acid dianhydride.

References:

US2016/376285,2016,A1 Location in patent:Paragraph 0113

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