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ChemicalBook >> CAS DataBase List >> N-HEXYLLITHIUM

N-HEXYLLITHIUM

N-HEXYLLITHIUM price.
  • $76.2 - $995.06
  • Product name: N-HEXYLLITHIUM
  • CAS: 21369-64-2
  • MF: C6H13Li
  • MW: 92.11
  • EINECS:404-950-0
  • MDL Number:MFCD00191446
  • Synonyms:n-Hexyllithium, 33 wt.% solution in n-hexane, AcroSeal;1-Lithiohexane;1-Hexyllithium;lithium,hexane;Lithium, hexyl-;HexyllithiuM, 2.5 M solution in Hexane, SpcSeal;N-HEXYLLITHIUM;HEXYLLITHIUM SOLUTION, ~2.3 M IN HEXANE
3 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
Package
  • 100ml
  • 1L
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0002761
  • Product descriptionHEXYLLITHIUM 95.00%
  • Packaging1L
  • Price$995.06
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number468568
  • Product descriptionHexyllithium solution 2.3M in hexane
  • Packaging100ml
  • Price$76.2
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number468568
  • Product descriptionHexyllithium solution 2.3M in hexane
  • Packaging1l
  • Price$293
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation OGM0002761 HEXYLLITHIUM 95.00% 1L $995.06 2021-12-16 Buy
Sigma-Aldrich 468568 Hexyllithium solution 2.3M in hexane 100ml $76.2 2024-03-01 Buy
Sigma-Aldrich 468568 Hexyllithium solution 2.3M in hexane 1l $293 2024-03-01 Buy

Properties

Boiling point :69 °C
Density :0.708 g/mL at 25 °C
vapor pressure :26.9-39.3hPa at 20-35℃
Flash point :16 °F
storage temp. :2-8°C
color :yellow-brown
Sensitive :Moisture Sensitive
BRN :3600261
Stability :Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons.
EPA Substance Registry System :Lithium, hexyl- (21369-64-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P307 IF exposed:
P370+P378 In case of fire: Use … for extinction.
P422 Store contents under …

Description

n-Hexyllithium [21369-64-2], C6H13Li, Mr 92.11, r 0.766 g/cm3 is a pyrophoric colorless and viscous liquid in the neat state. It is commercially available as a 33 % solution in technical-grade hexane. Its reactivity resembles that of n-butyllithium and it can thus principally be used for the same applications. An advantage is that it does not form gaseous byproducts in deprotonation reactions and on hydrolysis, but liquid hexane instead.

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