S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
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- $65 - $1396
- Product name: S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
- CAS: 929097-92-7
- MF: C56H41O4PSi2
- MW: 865.08
- EINECS:
- MDL Number:MFCD09265079
- Synonyms:(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%;(S)-(+)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(S)-TIPSY];(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate;(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(S)-2,2''-Dihydroxy-3,3''-bis(triphenylsilyl)-1,1''-binaphthalene cyclic phosphate;(11bS)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;SF110008
9 prices
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Brand
- Ambeed
- ChemScene
- Sigma-Aldrich
- Strem Chemicals
Package
- 10mg
- 100mg
- 250mg
- 1g
- 5g
- ManufacturerAmbeed
- Product numberA327179
- Product description(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%
- Packaging100mg
- Price$78
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA327179
- Product description(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%
- Packaging250mg
- Price$158
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA327179
- Product description(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%
- Packaging1g
- Price$398
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA327179
- Product description(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%
- Packaging5g
- Price$1396
- Updated2021-12-16
- Buy
- ManufacturerChemScene
- Product numberCS-B0723
- Product description(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diylhydrogenphosphate
- Packaging100mg
- Price$261
- Updated2021-12-16
- Buy
- ManufacturerChemScene
- Product numberCS-B0723
- Product description(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diylhydrogenphosphate
- Packaging1g
- Price$418
- Updated2021-12-16
- Buy
- ManufacturerSigma-Aldrich
- Product number680184
- Product description(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95%
- Packaging100mg
- Price$114.8
- Updated2024-03-01
- Buy
- ManufacturerStrem Chemicals
- Product number15-0341
- Product description(S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(S)-TiPSY]
- Packaging10mg
- Price$65
- Updated2024-03-01
- Buy
- ManufacturerStrem Chemicals
- Product number15-0341
- Product description(S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(S)-TiPSY]
- Packaging100mg
- Price$493
- Updated2024-03-01
- Buy
| Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|
| Ambeed | A327179 | (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98% | 100mg | $78 | 2021-12-16 | Buy |
| Ambeed | A327179 | (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98% | 250mg | $158 | 2021-12-16 | Buy |
| Ambeed | A327179 | (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98% | 1g | $398 | 2021-12-16 | Buy |
| Ambeed | A327179 | (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98% | 5g | $1396 | 2021-12-16 | Buy |
| ChemScene | CS-B0723 | (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diylhydrogenphosphate | 100mg | $261 | 2021-12-16 | Buy |
| ChemScene | CS-B0723 | (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diylhydrogenphosphate | 1g | $418 | 2021-12-16 | Buy |
| Sigma-Aldrich | 680184 | (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95% | 100mg | $114.8 | 2024-03-01 | Buy |
| Strem Chemicals | 15-0341 | (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(S)-TiPSY] | 10mg | $65 | 2024-03-01 | Buy |
| Strem Chemicals | 15-0341 | (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(S)-TiPSY] | 100mg | $493 | 2024-03-01 | Buy |
Properties
Melting point :329-335°C
alpha :+210° (c=1.0, CHCl3)
Density :1.32±0.1 g/cm3(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :1.17±0.20(Predicted)
form :solid
color :white to light-yellow
optical activity :[α]22/D +210°, c = 1 in chloroform
alpha :+210° (c=1.0, CHCl3)
Density :1.32±0.1 g/cm3(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :1.17±0.20(Predicted)
form :solid
color :white to light-yellow
optical activity :[α]22/D +210°, c = 1 in chloroform
Safety Information
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Description
(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:- In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.
- In the exo-selective cyclization of mupirocin methyl ester.
- In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.
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