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ChemicalBook >> CAS DataBase List >> Di-tert-Butyl azodicarboxylate

Di-tert-Butyl azodicarboxylate

Di-tert-Butyl azodicarboxylate price.
  • $5 - $1263.08
  • Product name: Di-tert-Butyl azodicarboxylate
  • CAS: 870-50-8
  • MF: C10H18N2O4
  • MW: 230.26
  • EINECS:212-796-9
  • MDL Number:MFCD00015001
  • Synonyms:Di-tert-butyl azodicarboxylate SynonyMs Azodicarboxylic acid di-tert-butyl ester;Bis(1,1-dimethylethyl)azodicarboxylate;NSC 109889;DI-TERT-BUTYL AZODICARBOXYALTE;Di-tert-butyl azodicarboxylate, 98% 5GR;Di-Tert-ButylAzodicarboxylate(Dbad);Di-(tert-butyl) diazene-1,2-dicarboxylate 98%;Di-tert-butyl azodicarboxylate purum, >=98.0% (GC)
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  • AHH
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Apolloscientific
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  • Biosynth Carbosynth
  • Frontier Specialty Chemicals
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  • 25gm:
  • ManufacturerAHH
  • Product numberMT-08226
  • Product descriptionDi-tert-butyl azodicarboxylate 98%
  • Packaging1000g
  • Price$752
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ95406
  • Product descriptionDi-tert-butylazodicarboxylate(DBAD)
  • Packaging1kg
  • Price$460
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL00294
  • Product descriptionDi-tert-butyl azodicarboxylate, 98%
  • Packaging5g
  • Price$47.9
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL00294
  • Product descriptionDi-tert-butyl azodicarboxylate, 98%
  • Packaging25g
  • Price$157
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number870508
  • Product descriptionDi-tert-butyl azodicarboxylate
  • Packaging1kg
  • Price$618
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA257862
  • Product descriptionDi-tert-butyldiazene-1,2-dicarboxylate 97%
  • Packaging1g
  • Price$5
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA257862
  • Product descriptionDi-tert-butyldiazene-1,2-dicarboxylate 97%
  • Packaging5g
  • Price$6
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA257862
  • Product descriptionDi-tert-butyldiazene-1,2-dicarboxylate 97%
  • Packaging10g
  • Price$9
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA257862
  • Product descriptionDi-tert-butyldiazene-1,2-dicarboxylate 97%
  • Packaging25g
  • Price$19
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA257862
  • Product descriptionDi-tert-butyldiazene-1,2-dicarboxylate 97%
  • Packaging100g
  • Price$48
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA257862
  • Product descriptionDi-tert-butyldiazene-1,2-dicarboxylate 97%
  • Packaging500g
  • Price$234
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0029354
  • Product descriptionDI-TERT-BUTYL AZODICARBOXYLATE 95.00%
  • Packaging5G
  • Price$834.13
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0029354
  • Product descriptionDI-TERT-BUTYL AZODICARBOXYLATE 95.00%
  • Packaging25G
  • Price$1263.08
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR5753
  • Product descriptionDi-(tert-butyl)diazene-1,2-dicarboxylate 98%
  • Packaging5g
  • Price$21
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR5753
  • Product descriptionDi-(tert-butyl)diazene-1,2-dicarboxylate 98%
  • Packaging25g
  • Price$83
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR5753
  • Product descriptionDi-(tert-butyl)diazene-1,2-dicarboxylate 98%
  • Packaging100g
  • Price$225
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-08226 Di-tert-butyl azodicarboxylate 98% 1000g $752 2021-12-16 Buy
AK Scientific J95406 Di-tert-butylazodicarboxylate(DBAD) 1kg $460 2021-12-16 Buy
Alfa Aesar L00294 Di-tert-butyl azodicarboxylate, 98% 5g $47.9 2024-03-01 Buy
Alfa Aesar L00294 Di-tert-butyl azodicarboxylate, 98% 25g $157 2024-03-01 Buy
Alichem 870508 Di-tert-butyl azodicarboxylate 1kg $618 2021-12-16 Buy
Ambeed A257862 Di-tert-butyldiazene-1,2-dicarboxylate 97% 1g $5 2021-12-16 Buy
Ambeed A257862 Di-tert-butyldiazene-1,2-dicarboxylate 97% 5g $6 2021-12-16 Buy
Ambeed A257862 Di-tert-butyldiazene-1,2-dicarboxylate 97% 10g $9 2021-12-16 Buy
Ambeed A257862 Di-tert-butyldiazene-1,2-dicarboxylate 97% 25g $19 2021-12-16 Buy
Ambeed A257862 Di-tert-butyldiazene-1,2-dicarboxylate 97% 100g $48 2021-12-16 Buy
Ambeed A257862 Di-tert-butyldiazene-1,2-dicarboxylate 97% 500g $234 2021-12-16 Buy
American Custom Chemicals Corporation CHM0029354 DI-TERT-BUTYL AZODICARBOXYLATE 95.00% 5G $834.13 2021-12-16 Buy
American Custom Chemicals Corporation CHM0029354 DI-TERT-BUTYL AZODICARBOXYLATE 95.00% 25G $1263.08 2021-12-16 Buy
Apolloscientific OR5753 Di-(tert-butyl)diazene-1,2-dicarboxylate 98% 5g $21 2021-12-16 Buy
Apolloscientific OR5753 Di-(tert-butyl)diazene-1,2-dicarboxylate 98% 25g $83 2021-12-16 Buy
Apolloscientific OR5753 Di-(tert-butyl)diazene-1,2-dicarboxylate 98% 100g $225 2021-12-16 Buy

Properties

Melting point :89-92 °C(lit.)
Boiling point :287.1±9.0 °C(Predicted)
Density :1.06±0.1 g/cm3(Predicted)
storage temp. :2-8°C
solubility :Chloroform (Sparingly), Methanol (Slightly)
form :Crystals or Crystalline Powder
color :Yellow
Water Solubility :Insoluble
Sensitive :Light Sensitive
BRN :1911434
InChI :InChI=1S/C10H18N2O4/c1-9(2,3)15-7(13)11-12-8(14)16-10(4,5)6/h1-6H3
InChIKey :QKSQWQOAUQFORH-VAWYXSNFSA-N
SMILES :N(C(OC(C)(C)C)=O)=NC(OC(C)(C)C)=O
CAS DataBase Reference :870-50-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning GHS hazard pictograms P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger GHS hazard pictograms
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

Description

Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates. It is also used in the electrophilic amination of beta-keto esters catalyzed by an axially chiral guanidine. It serves as a precursor in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such as L-proline or (S)-2-pyrrolidinyl tetrazole. It is also utilized in the asymmetric Friedel-Crafts amination through a chiral organocatalyst. Further, it acts as a reactant for preparation of hexapeptide key fragments through stereo selective selenocyclization/oxidative deselenylation reactions. In addition to this, it is employed as a starting material in the synthesis of pyrroloisoquinoline template through stereoselective N-acyliminium-mediated cyclization and enolate amination for preparation of peptidomimetic compounds and Barbier-type propargylation reactions.

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