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ChemicalBook >> CAS DataBase List >> 9-Borabicyclo[3.3.1]nonane

9-Borabicyclo[3.3.1]nonane

9-Borabicyclo[3.3.1]nonane price.
  • $45 - $7249.94
  • Product name: 9-Borabicyclo[3.3.1]nonane
  • CAS: 280-64-8
  • MF: C8H15B
  • MW: 122.02
  • EINECS:206-000-9
  • MDL Number:MFCD00074742
  • Synonyms:9-BORABICYCLO(3.3.1)NONANE SOLUTION, ~0. 5 M IN THF;9-Borabicyclo[3.3.1]nonane, 0.5M solution in THF;9-BBN,9-BORABICYCLO[3.3.1]NONANE;9-BORABICYCLO[3.3.1]NONANE (9BBN);9-BBN(0.5M in toluene);9-Borabicyclo[3.3.1]nonane0.5M solution in THFAcroSeal§3;1,5-(Boranediyl)cyclooctane;9-Borabicyclo[3.3.1]nonane, 0.5M solution inHexane
15 prices
Selected condition:
Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Sigma-Aldrich
  • TRC
Package
  • 50ml
  • 100g
  • 4x25ml
  • 100ml
  • 500ml
  • 800ml
  • 1l
  • 8L
  • 18L
  • ManufacturerAlfa Aesar
  • Product numberH52287
  • Product description9-BBN monomer, 97%, 0.5M in THF
  • Packaging100ml
  • Price$47.6
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH52287
  • Product description9-BBN monomer, 97%, 0.5M in THF
  • Packaging500ml
  • Price$180
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH52287
  • Product description9-BBN monomer, 97% 0.5M in THF
  • Packaging800ml
  • Price$444
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0011665
  • Product description9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00%
  • Packaging800ML
  • Price$6549.43
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0011665
  • Product description9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00%
  • Packaging8L
  • Price$7249.94
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB11143
  • Product description9-BBN monomer - 0.5M solution in THF
  • Packaging100g
  • Price$150
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number151076
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
  • Packaging4x25ml
  • Price$86.3
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number151076
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
  • Packaging100ml
  • Price$90.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number459496
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes
  • Packaging100ml
  • Price$125
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number151076
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
  • Packaging800ml
  • Price$447
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number459496
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes
  • Packaging1l
  • Price$1010
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number151076
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.5?M in THF
  • Packaging18L
  • Price$2184
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number151076
  • Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
  • Packaging8l
  • Price$2230
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberB675268
  • Product description9-Borabicyclononane
  • Packaging50ml
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerTRC
  • Product numberB675268
  • Product description9-Borabicyclononane
  • Packaging800ml
  • Price$425
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar H52287 9-BBN monomer, 97%, 0.5M in THF 100ml $47.6 2021-12-16 Buy
Alfa Aesar H52287 9-BBN monomer, 97%, 0.5M in THF 500ml $180 2021-12-16 Buy
Alfa Aesar H52287 9-BBN monomer, 97% 0.5M in THF 800ml $444 2021-12-16 Buy
American Custom Chemicals Corporation BOR0011665 9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00% 800ML $6549.43 2021-12-16 Buy
American Custom Chemicals Corporation BOR0011665 9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00% 8L $7249.94 2021-12-16 Buy
Biosynth Carbosynth FB11143 9-BBN monomer - 0.5M solution in THF 100g $150 2021-12-16 Buy
Sigma-Aldrich 151076 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF 4x25ml $86.3 2024-03-01 Buy
Sigma-Aldrich 151076 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF 100ml $90.8 2024-03-01 Buy
Sigma-Aldrich 459496 9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes 100ml $125 2024-03-01 Buy
Sigma-Aldrich 151076 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF 800ml $447 2024-03-01 Buy
Sigma-Aldrich 459496 9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes 1l $1010 2023-06-20 Buy
Sigma-Aldrich 151076 9-Borabicyclo[3.3.1]nonane solution 0.5?M in THF 18L $2184 2024-03-01 Buy
Sigma-Aldrich 151076 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF 8l $2230 2024-03-01 Buy
TRC B675268 9-Borabicyclononane 50ml $45 2021-12-16 Buy
TRC B675268 9-Borabicyclononane 800ml $425 2021-12-16 Buy

Properties

Melting point :140-142 °C
Boiling point :68-70 °C
Density :0.894 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
solubility :Miscible with ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane, dimethoxyethane, diglyme and dioxane.
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :605509
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) InChIKey :FEJUGLKDZJDVFY-OCAPTIKFSA-N
EPA Substance Registry System :9-Borabicyclo[3.3.1]nonane (280-64-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

9-BBN monomer acts as a selective hydroboration reagent in synthetic organic chemistry. It is employed in Suzuki reactions as well as in the preparation of terminal alcohols by the region selective addition of alkenes followed by oxidative cleavage using hydrogen peroxide. It is also used in copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides. It acts as a protecting group for alkenes. Further, it is used as a reactant for Hetero-Diels-Alder reaction for the synthesis of spirocyclic alkaloids. In addition to this, it is used in intramolecular insertion of alkenes into palladium-nitrogen bonds.

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