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ChemicalBook >> CAS DataBase List >> (R)-(+)-2-Methyl-2-propanesulfinamide

(R)-(+)-2-Methyl-2-propanesulfinamide

(R)-(+)-2-Methyl-2-propanesulfinamide price.
  • $4 - $1386.11
  • Product name: (R)-(+)-2-Methyl-2-propanesulfinamide
  • CAS: 196929-78-9
  • MF: C4H11NOS
  • MW: 121.2
  • EINECS:676-338-3
  • MDL Number:MFCD05861479
  • Synonyms:R- tert butyl sulfenaMide;(R)-(+)-TERT-BUTANESULFINAMIDE;(R)-(+)-T-BUTANESULFINAMIDE;(R)-(+)-T-BUTYLMETHYLSULFINAMIDE;(R)-(+)-T-BUTYLSULFINAMIDE;(R)-(+)-TERT-BUTYLSULFINAMIDE;(R)-(+)-TERT-BUTYL SULPHINAMIDE;(R)-(+)-2-METHYL-PROPANE-2-SULFINIC ACID AMIDE
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  • Acrotein
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  • ManufacturerAcrotein
  • Product numberAM-2911
  • Product description(R)-tert-Butylsulfinamide 97%
  • Packaging100g
  • Price$179.67
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberAM-2911
  • Product description(R)-tert-Butylsulfinamide 97%
  • Packaging250g
  • Price$348.33
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-23986
  • Product description(R)-tert-Butanesulfinamide 98%
  • Packaging10g
  • Price$650
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberF308
  • Product description(R)-(+)-2-Methyl-2-propanesulfinamide
  • Packaging5g
  • Price$34
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90298
  • Product description(R)-(+)-2-Methyl-2-propanesulfinamide
  • Packaging25g
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90298
  • Product description(R)-(+)-2-Methyl-2-propanesulfinamide
  • Packaging100g
  • Price$180
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product numberH27724
  • Product description(R)-(+)-2-Methyl-2-propanesulfinamide, 98%
  • Packaging1g
  • Price$60.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27724
  • Product description(R)-(+)-2-Methyl-2-propanesulfinamide, 98%
  • Packaging5g
  • Price$239
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27724
  • Product description(R)-(+)-2-Methyl-2-propanesulfinamide, 98%
  • Packaging25g
  • Price$720.65
  • Updated2024-03-01
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  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging1g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging5g
  • Price$8
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging10g
  • Price$13
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging25g
  • Price$30
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging100g
  • Price$93
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging500g
  • Price$358
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA348213
  • Product description(R)-2-Methyl-2-propanesulfinamide 98%
  • Packaging1kg
  • Price$642
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AM-2911 (R)-tert-Butylsulfinamide 97% 100g $179.67 2021-12-16 Buy
Acrotein AM-2911 (R)-tert-Butylsulfinamide 97% 250g $348.33 2021-12-16 Buy
AHH MT-23986 (R)-tert-Butanesulfinamide 98% 10g $650 2021-12-16 Buy
AK Scientific F308 (R)-(+)-2-Methyl-2-propanesulfinamide 5g $34 2021-12-16 Buy
AK Scientific J90298 (R)-(+)-2-Methyl-2-propanesulfinamide 25g $60 2021-12-16 Buy
AK Scientific J90298 (R)-(+)-2-Methyl-2-propanesulfinamide 100g $180 2021-12-16 Buy
Alfa Aesar H27724 (R)-(+)-2-Methyl-2-propanesulfinamide, 98% 1g $60.65 2024-03-01 Buy
Alfa Aesar H27724 (R)-(+)-2-Methyl-2-propanesulfinamide, 98% 5g $239 2024-03-01 Buy
Alfa Aesar H27724 (R)-(+)-2-Methyl-2-propanesulfinamide, 98% 25g $720.65 2024-03-01 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 1g $6 2021-12-16 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 5g $8 2021-12-16 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 10g $13 2021-12-16 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 25g $30 2021-12-16 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 100g $93 2021-12-16 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 500g $358 2021-12-16 Buy
Ambeed A348213 (R)-2-Methyl-2-propanesulfinamide 98% 1kg $642 2021-12-16 Buy

Properties

Melting point :103-107 °C(lit.)
Boiling point :220.0±23.0 °C(Predicted)
alpha :4 º (c=1, CHCl3 + amylenes)
Density :0.903 g/mL at 25 °C
refractive index :4 ° (C=1, CHCl3)
Flash point :-17℃
storage temp. :2-8°C
solubility :Soluble in chloroform, methanol, tetrahydrofuran, dichloromethane, dimethyl sulfoxide and most organic solvents.
form :Powder
pka :10.11±0.50(Predicted)
color :White, light pink, light yellow to brown
optical activity :[α]22/D +1.0°, c = 0.5% in chloroform
Stability :store cold
InChIKey :CESUXLKAADQNTB-SSDOTTSWSA-N
CAS DataBase Reference :196929-78-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

(R)-(+)-2-Methyl-2-propanesulfinamide is a chiral ligand, which is used in pharmaceutical compositions. Further, it is used in the preparation of beta-chloro sulfinamides in the synthesis of chiral azridines. It is involved in the preparation of organocatalyst for enantioselective reduction of imines. It serves as a reagent for synthesizing chiral amines. In addition to this, it is converted into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones which undergoes iridium-catalyzed asymmetric hydrogenation of olefins.

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