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ChemicalBook >> CAS DataBase List >> LITHIUM TETRACHLOROCUPRATE

LITHIUM TETRACHLOROCUPRATE

LITHIUM TETRACHLOROCUPRATE price.
  • $52.64 - $1695
  • Product name: LITHIUM TETRACHLOROCUPRATE
  • CAS: 15489-27-7
  • MF: Cl4CuLi-
  • MW: 212.29
  • EINECS:203-726-8
  • MDL Number:MFCD00011081
  • Synonyms:LITHIUM TETRACHLOROCUPRATE;LITHIUM TETRACHLOROCUPRATE(II);DILITHIUM TETRACHLOROCUPRATE;DI-LITHIUM TETRACHLOROCUPRATE(II);Dilithium tetrachlorocuprate(II) solution;DILITHIUM TETRACHLOROCUPRATE, 0.1M SOLUT ION IN TETRAHYDROFURAN;0.1MinTHF;Dilithium tetrachlorocuprate, 0.1 M solution in THF
11 prices
Selected condition：
Brand
  • Alfa Aesar
  • Chem-Impex
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 500mg
  • 100ml
  • 500ml
  • 800ml
  • ManufacturerAlfa Aesar
  • Product number020620
  • Product descriptionLithium tetrachlorocuprate, 0.1M in THF
  • Packaging100ml
  • Price$72.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number020620
  • Product descriptionLithium tetrachlorocuprate, 0.1M in THF
  • Packaging500ml
  • Price$288.65
  • Updated2024-03-01
  • Buy
  • ManufacturerChem-Impex
  • Product number40703
  • Product descriptionDilithiumtetrachlorocopper(II)(ca.2.5%inTetrahydrofuran,ca.0.1mol/L),Concentration=2.2-2.9% Concentration=2.2-2.9%
  • Packaging100ML
  • Price$52.64
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number40703
  • Product descriptionDilithiumtetrachlorocopper(II)(ca.2.5%inTetrahydrofuran,ca.0.1mol/L),Concentration=2.2-2.9%Hazmat Concentration=2.2-2.9%
  • Packaging500ML
  • Price$158.41
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number224308
  • Product descriptionDilithium tetrachlorocuprate(II) solution 0.1 M in THF
  • Packaging800ml
  • Price$156.6
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number224308
  • Product descriptionDilithium tetrachlorocuprate(II) solution 0.1 M in THF
  • Packaging100ml
  • Price$347
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number03-4500
  • Product descriptionLithium tetrachlorocuprate, 0.1M in THF
  • Packaging100ml
  • Price$88
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number03-4500
  • Product descriptionLithium tetrachlorocuprate, 0.1M in THF
  • Packaging500ml
  • Price$333
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberD4395
  • Product descriptionDilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L)
  • Packaging100mL
  • Price$59
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberD4395
  • Product descriptionDilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L)
  • Packaging500mL
  • Price$144
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberD459905
  • Product descriptionDilithiumTetrachlorocuprate
  • Packaging500mg
  • Price$1695
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 020620 Lithium tetrachlorocuprate, 0.1M in THF 100ml $72.65 2024-03-01 Buy
Alfa Aesar 020620 Lithium tetrachlorocuprate, 0.1M in THF 500ml $288.65 2024-03-01 Buy
Chem-Impex 40703 Dilithiumtetrachlorocopper(II)(ca.2.5%inTetrahydrofuran,ca.0.1mol/L),Concentration=2.2-2.9% Concentration=2.2-2.9% 100ML $52.64 2021-12-16 Buy
Chem-Impex 40703 Dilithiumtetrachlorocopper(II)(ca.2.5%inTetrahydrofuran,ca.0.1mol/L),Concentration=2.2-2.9%Hazmat Concentration=2.2-2.9% 500ML $158.41 2021-12-16 Buy
Sigma-Aldrich 224308 Dilithium tetrachlorocuprate(II) solution 0.1 M in THF 800ml $156.6 2024-03-01 Buy
Sigma-Aldrich 224308 Dilithium tetrachlorocuprate(II) solution 0.1 M in THF 100ml $347 2024-03-01 Buy
Strem Chemicals 03-4500 Lithium tetrachlorocuprate, 0.1M in THF 100ml $88 2024-03-01 Buy
Strem Chemicals 03-4500 Lithium tetrachlorocuprate, 0.1M in THF 500ml $333 2024-03-01 Buy
TCI Chemical D4395 Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L) 100mL $59 2024-03-01 Buy
TCI Chemical D4395 Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L) 500mL $144 2024-03-01 Buy
TRC D459905 DilithiumTetrachlorocuprate 500mg $1695 2021-12-16 Buy

Properties

Boiling point :66°C
Density :0.91 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
solubility :Difficult to mix.
form :Liquid
Specific Gravity :0.91
color :Dark orange
Sensitive :Moisture Sensitive
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines.

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