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ChemicalBook >> CAS DataBase List >> t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3

$31 - $1702
Product name: t-BuBrettPhos Palladacycle Gen. 3
CAS: 1536473-72-9
MF: C44H63NO5PPdS-
MW: 855.433481
EINECS:-0
MDL Number:MFCD25976528
Synonyms:Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%;METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3];t-BuBrettPhos Palladacycle Gen. 3;Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3];Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.;Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II);[2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle

Price26 Properties Safety Information Description

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Alichem
Ambeed
Arctom
Chemenu
Crysdot
Sigma-Aldrich
Strem Chemicals
TRC

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100mg
250mg
500MG
1g
2G
5g
10g

ManufacturerAlichem
Product number1536473729
Product descriptiontBuBrettPhosPdG3
Packaging5g
Price$856.8
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging100mg
Price$31
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging250mg
Price$76
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging1g
Price$153
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA206000
Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
Packaging5g
Price$620
Updated2021-12-16
Buy

ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
Packaging250mg
Price$70
Updated2021-12-16
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ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
Packaging1g
Price$195
Updated2021-12-16
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ManufacturerArctom
Product numberSY073202
Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
Packaging5g
Price$750
Updated2021-12-16
Buy

ManufacturerChemenu
Product numberCM102765
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%
Packaging1g
Price$341
Updated2021-12-16
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ManufacturerChemenu
Product numberCM102765
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%
Packaging5g
Price$1021
Updated2021-12-16
Buy

ManufacturerChemenu
Product numberCM102765
Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%
Packaging10g
Price$1702
Updated2021-12-16
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ManufacturerCrysdot
Product numberCD52001017
Product descriptiontBuBrettPhosPdG3 95+%
Packaging250mg
Price$109
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD52001017
Product descriptiontBuBrettPhosPdG3 95+%
Packaging1g
Price$279
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD52001017
Product descriptiontBuBrettPhosPdG3 95+%
Packaging5g
Price$835
Updated2021-12-16
Buy

ManufacturerSigma-Aldrich
Product number745979
Product descriptiontBuBrettPhos Pd G3 96%
Packaging100MG
Price$81.6
Updated2024-03-01
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ManufacturerSigma-Aldrich
Product number745979
Product descriptiontBuBrettPhos Pd G3 96%
Packaging500MG
Price$147
Updated2024-03-01
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Alichem	1536473729	tBuBrettPhosPdG3	5g	$856.8	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	100mg	$31	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	250mg	$76	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	1g	$153	2021-12-16	Buy
Ambeed	A206000	[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%	5g	$620	2021-12-16	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%	250mg	$70	2021-12-16	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%	1g	$195	2021-12-16	Buy
Arctom	SY073202	Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%	5g	$750	2021-12-16	Buy
Chemenu	CM102765	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%	1g	$341	2021-12-16	Buy
Chemenu	CM102765	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%	5g	$1021	2021-12-16	Buy
Chemenu	CM102765	Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%	10g	$1702	2021-12-16	Buy
Crysdot	CD52001017	tBuBrettPhosPdG3 95+%	250mg	$109	2021-12-16	Buy
Crysdot	CD52001017	tBuBrettPhosPdG3 95+%	1g	$279	2021-12-16	Buy
Crysdot	CD52001017	tBuBrettPhosPdG3 95+%	5g	$835	2021-12-16	Buy
Sigma-Aldrich	745979	tBuBrettPhos Pd G3 96%	100MG	$81.6	2024-03-01	Buy
Sigma-Aldrich	745979	tBuBrettPhos Pd G3 96%	500MG	$147	2024-03-01	Buy

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Properties

Melting point :119-131°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
color :brown-green
InChIKey :VKLHIPFGYVFUGT-UHFFFAOYSA-N
CAS DataBase Reference :1536473-72-9

Safety Information

Symbol(GHS):

Signal word:

Danger

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	Pictogram	P-Codes

Precautionary statements:

P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313	IF exposed or concerned: Get medical advice/attention.
P405	Store locked up.
P501	Dispose of contents/container to..…

Description

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

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Suppliers and manufacturers

career henan chemical co

$1.00 /1g
t-BuBrettPhos Palladacycle Gen. 3 CAS:1536473-72-9

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t-BuBrettPhos Palladacycle Gen. 3

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