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ChemicalBook >> CAS DataBase List >> 1,4-Benzoquinone

1,4-Benzoquinone

1,4-Benzoquinone price.
  • $10 - $7780
  • Product name: 1,4-Benzoquinone
  • CAS: 106-51-4
  • MF: C6H4O2
  • MW: 108.09
  • EINECS:203-405-2
  • MDL Number:MFCD00001591
  • Synonyms:1,4-benzoquinone Quinone;1,4-Benzoquinone, 99+%;BENZOQUINONE, 1,4-(SG);P-BENZOQUINONE / QUINONE;P-BENZOZUINONE;Benzoquinone,90%;p-Benzoquinone solution;p-Benzoquione
44 prices
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Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Cayman Chemical
  • Chemenu
  • Chem-Impex
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
  • Usbiological
Package
  • 200mg
  • 1g
  • 2.500g
  • 5g
  • 10G
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  • 50g
  • 100g
  • 250g
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  • 1kg
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  • 5kg
  • 25kg
  • 50kg
  • ManufacturerAlfa Aesar
  • Product numberA13162
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging100g
  • Price$35.1
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13162
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging250g
  • Price$42.1
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13162
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging1000g
  • Price$124
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13162
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging5000g
  • Price$541
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0031712
  • Product descriptionPARA-BENZOQUINONE 95.00%
  • Packaging10G
  • Price$115.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0031712
  • Product descriptionPARA-BENZOQUINONE 95.00%
  • Packaging25G
  • Price$1099.97
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0031712
  • Product descriptionPARA-BENZOQUINONE 95.00%
  • Packaging500G
  • Price$4326.72
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB01020
  • Product description1,4-Benzoquinone
  • Packaging250g
  • Price$62.5
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB01020
  • Product description1,4-Benzoquinone
  • Packaging500g
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB01020
  • Product description1,4-Benzoquinone
  • Packaging1kg
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB01020
  • Product description1,4-Benzoquinone
  • Packaging2Kg
  • Price$220
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB01020
  • Product description1,4-Benzoquinone
  • Packaging5kg
  • Price$475
  • Updated2021-12-16
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  • ManufacturerCayman Chemical
  • Product number27560
  • Product description1,4-Benzoquinone
  • Packaging100g
  • Price$36
  • Updated2024-03-01
  • Buy
  • ManufacturerChemenu
  • Product numberCM328783
  • Product descriptioncyclohexa-2,5-diene-1,4-dione 95%+
  • Packaging1000g
  • Price$80
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number37187
  • Product descriptionp-Benzoquinone,≥99%(GC)Hazmat ≥99%(GC)
  • Packaging100G
  • Price$20.6
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number37187
  • Product descriptionp-Benzoquinone,98%(GC) 98%(GC)
  • Packaging250G
  • Price$39.2
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar A13162 p-Benzoquinone, 98+% 100g $35.1 2024-03-01 Buy
Alfa Aesar A13162 p-Benzoquinone, 98+% 250g $42.1 2024-03-01 Buy
Alfa Aesar A13162 p-Benzoquinone, 98+% 1000g $124 2024-03-01 Buy
Alfa Aesar A13162 p-Benzoquinone, 98+% 5000g $541 2024-03-01 Buy
American Custom Chemicals Corporation CHM0031712 PARA-BENZOQUINONE 95.00% 10G $115.5 2021-12-16 Buy
American Custom Chemicals Corporation CHM0031712 PARA-BENZOQUINONE 95.00% 25G $1099.97 2021-12-16 Buy
American Custom Chemicals Corporation CHM0031712 PARA-BENZOQUINONE 95.00% 500G $4326.72 2021-12-16 Buy
Biosynth Carbosynth FB01020 1,4-Benzoquinone 250g $62.5 2021-12-16 Buy
Biosynth Carbosynth FB01020 1,4-Benzoquinone 500g $90 2021-12-16 Buy
Biosynth Carbosynth FB01020 1,4-Benzoquinone 1kg $120 2021-12-16 Buy
Biosynth Carbosynth FB01020 1,4-Benzoquinone 2Kg $220 2021-12-16 Buy
Biosynth Carbosynth FB01020 1,4-Benzoquinone 5kg $475 2021-12-16 Buy
Cayman Chemical 27560 1,4-Benzoquinone 100g $36 2024-03-01 Buy
Chemenu CM328783 cyclohexa-2,5-diene-1,4-dione 95%+ 1000g $80 2021-12-16 Buy
Chem-Impex 37187 p-Benzoquinone,≥99%(GC)Hazmat ≥99%(GC) 100G $20.6 2021-12-16 Buy
Chem-Impex 37187 p-Benzoquinone,98%(GC) 98%(GC) 250G $39.2 2021-12-16 Buy

Properties

Melting point :113-115 °C(lit.)
Boiling point :293°C
Density :1.31
vapor density :3.73 (vs air)
vapor pressure :0.1 mm Hg ( 25 °C)
refractive index :n20/D 1.453
Flash point :38°C
storage temp. :room temp
solubility :10g/l
form :Powder
pka :7.7
color :Yellow to green
Odor :irritant odor
PH :4 (1g/l, H2O, 20℃)
Water Solubility :10 g/L (25 ºC)
Merck :14,8074
BRN :773967
Exposure limits :TLV-TWA 0.4 mg/m3 (0.1 ppm); STEL 1.2 mg/m3 (0.3 ppm) (ACGIH); IDLH 75 ppm (NIOSH).
Stability :Stable, but light sensitive. Incompatible with strong oxidizing agents. Flammable.
InChIKey :AZQWKYJCGOJGHM-UHFFFAOYSA-N
LogP :0.1-0.3 at 23℃ and pH4.8-5.3
CAS DataBase Reference :106-51-4(CAS DataBase Reference)
IARC :3 (Vol. 15, Sup 7, 71) 1999
NIST Chemistry Reference :p-Benzoquinone(106-51-4)
EPA Substance Registry System :Quinone (106-51-4)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,4-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.

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