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Chemical Safety Data Sheet MSDS / SDS

Benzyltriethylammonium chloride

Revision Date:2024-12-21Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: Benzyltriethylammonium chloride
  • CBnumber: CB2145040
  • CAS: 56-37-1
  • EINECS Number: 200-270-1
  • Synonyms: TEBAC,TEBA

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordWarning
Precautionary statements
P405 Store locked up.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash skin thouroughly after handling.
P264 Wash hands thoroughly after handling.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
Hazard statements
H335 May cause respiratory irritation
H319 Causes serious eye irritation
H315 Causes skin irritation
H303 May be harmfulif swallowed

SECTION 3: Composition/information on ingredients

Substance

  • Product name: Benzyltriethylammonium chloride
  • Synonyms: TEBAC,TEBA
  • CAS: 56-37-1
  • EC number: 200-270-1
  • MF: C13H22ClN
  • MW: 227.77

SECTION 4: First aid measures

Description of first aid measures

General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

No data available

NFPA 704

2
2
0
HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
FIRE 2 Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur and multiple finely divided suspended solids that do not require heating before ignition can occur. Flash point between 37.8 and 93.3 °C (100 and 200 °F). (e.g. diesel fuel, sulfur)
REACT 0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. hygroscopic

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment
Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU

EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearancewhite crystalline
  • OdourNo data available
  • Odour ThresholdNo data available d) pH 6,0 - 8,0 at 100 g/l at 20 °C Melting point/freezing point Initial boiling point and boiling range Melting point/range: 190 - 192 °C - dec. 444,8 °C at 1013 hPa Flash point >275 °C - closed cup Evaporation rate No data available Flammability (solid, gas) Upper/lower flammability or explosive limits No data available No data available Vapour pressure No data available Vapour density No data available Relative density No data available Water solubility No data available Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature No data available No data available 185 °C - Viscosity No data available Explosive properties No data available Oxidizing properties No data available
  • Melting point/freezing pointMelting point/range: 190 - 192 °C - dec.
  • Initial boiling point and boiling range 444,8 °C at 1013 hPa
  • Flash point>275 °C - closed cup
  • Evaporation rate>100°C
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsNo data available
  • Vapour pressureNo data available
  • Vapour densityNo data available
  • Relative densityNo data available
  • Water solubilityNo data available
  • Partition coefficient: n-octanol/waterH2O: 0.1 g/mL, clear
  • Autoignition temperatureNo data available
  • Decomposition temperature 185 °C -
  • Viscosity185°C
  • Explosive propertiesNo data available
  • Oxidizing propertiesNo data available

Other safety information

Bulk density 0,55 g/l

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Other decomposition products - No data available In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - 2.219 mg/kg
Remarks: Behavioral:Somnolence (general depressed activity). Gastrointestinal:Changes in structure or function of salivary glands. Skin and Appendages: Other: Hair.
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: BO8275000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Toxicity
LD50 orally in Rabbit: 2219 mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish
LC50 - Pimephales promelas (fathead minnow) - 161 mg/l - 96 h

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

No data available

SECTION 13: Disposal considerations

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

SECTION 14: Transport information

SECTION 14: Transport information

IATA:
IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:
IATA:IMDG:IATA:

UN number

ADR/RID:IMDG:IATA:

UN number

ADR/RID: 3295 IMDG: 3295 IATA: 3295
ADR/RID: 1987 IMDG: 1987 IATA: 1987
ADR/RID: FLAMMABLE LIQUID, N.O.S. (1-Bromopropene) IMDG: FLAMMABLE LIQUID, N.O.S. (1-Bromopropene) IATA: Flammable liquid, n.o.s. (1-Bromopropene)
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: 3272 IMDG: 3272 IATA: 3272
ADR/RID: - IMDG: - IATA: -
ADR/RID: 3399 IMDG: 3399 IATA: 3399
ADR/RID: - IMDG: - IATA: -
ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA: 3 (6.1)
ADR/RID: 1463 IMDG: 1463 IATA: 1463
ADR/RID: 3 IMDG: 3 IATA: 3

Packaging group

ADR/RID: III IMDG: III IATA: III
ADR/RID: CHROMIUM TRIOXIDE, ANHYDROUS IMDG: CHROMIUM TRIOXIDE, ANHYDROUS IATA: Chromium trioxide, anhydrous
ADR/RID: II IMDG: II IATA: II
ADR/RID: - IMDG: - IATA: -
ADR/RID: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE (Xylene, Sodium acetylide) IMDG: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE (Xylene, Sodium acetylide) IATA: Organometallic substance, liquid, water-reactive, flammable (Xylene, Sodium acetylide) Passenger Aircraft: Not permitted for transport
ADR/RID: - IMDG: - IATA: -
ADR/RID: ESTERS, N.O.S. (1,1,1-Trimethoxypentane) IMDG: ESTERS, N.O.S. (1,1,1-Trimethoxypentane) IATA: Esters, n.o.s. (1,1,1-Trimethoxypentane)
ADR/RID: II IMDG: II IATA: II
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: ALCOHOLS, N.O.S. (4-Methylpentan-1-ol) IMDG: ALCOHOLS, N.O.S. (4-Methylpentan-1-ol) IATA: Alcohols, n.o.s. (4-Methylpentan-1-ol)
ADR/RID: HYDROCARBONS, LIQUID, N.O.S. (1,9-decadiene) IMDG: HYDROCARBONS, LIQUID, N.O.S. (1,9-decadiene) IATA: Hydrocarbons, liquid, n.o.s.

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: II IMDG: II IATA: II
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: no IMDG Marine pollutant: no IATA: no Special precautions for user Further information Not classified as dangerous in the meaning of transport regulations.
ADR/RID: 4.3 (3) IMDG: 4.3 (3) IATA: 4.3 (3)
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: 5.1 (6.1, 8) IMDG: 5.1 (6.1, 8) IATA: 5.1 (6.1)(8)
ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

No data available
ADR/RID: II IMDG: II IATA: II
No data available
ADR/RID: I IMDG: I IATA: I
ADR/RID: III IMDG: III IATA: III
No data available
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: III IMDG: III IATA: III
ADR/RID: III IMDG: III IATA: III
No data available

Environmental hazards

ADR/RID: yes IMDG Marine pollutant: yes IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
No data available
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: yes IMDG Marine pollutant: yes IATA: no

Special precautions for user

No data available
No data available
No data available
No data available
No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/
United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
EC Inventory:Listed.
European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

SECTION 16: Other information

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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