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Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
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Immediate First Aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Aromatic hydrocarbons and related compounds
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
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Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. Keep in suitable, closed containers for disposal.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
| Component | 2,6-xylidinium chloride |
|---|---|
| CAS No. | 21436-98-6 |
|
Recommended Exposure Limit: 10-hour Time-Weighted Average: 2 ppm (10 mg/cu m). Skin. |
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
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Characteristic odor
188°C(lit.)
131°C/2.5mmHg(lit.)
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57°C(lit.)
520 deg C
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1.7 mPa.s (dynamic) at 50 deg C
log Kow = 1.84
0.13mmHg at 25°C
0.9842 g/cu cm at 20 deg C
4.2 (Air = 1)
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Stable under recommended storage conditions.
This chemical is a combustible liquid. Xylidines
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Incompatible materials: Acids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates, halogens.
When heated to decomposition it emits toxic fumes of /nitrogen oxides/.
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Evaluation: There is inadequate evidence in humans for the carcinogenicity of 2,6-dimethylaniline. There is sufficient evidence in experimental animals for the carcinogenicity of 2,6-dimethylaniline. Overall evaluation: 2,6-dimethylaniline is possibly carcinogenic to humans (Group 2B).
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AEROBIC: A Warburg respirometer study utilizing an activated sludge seed and 6 hr of incubation resulted in a 2,6-xylidine depletion of 33-37% at a concentration of 20 ppm(1). In a 6 week soil degradation study using (14)C-labelled 2,6-xylidine, 8.4% of applied radioactivity was recovered via CO2 evolution in non-autoclaved soil while 0% CO2 evolution occurred in autoclaved soil(2). In a soil degradation study conducted in glass vessels using Chernozem soil, 2,6-xylidine (at 500 mg/L) was degraded after 3 days of incubation with >90% recovered in transformation products(3). Using OECD Guideline 301F (Ready Biodegradability: Manometric Respirometry Test), 2,6-xylidine (at 100 mg/L) reached 4, 8, 25, 38 and 69% of its theoretical BOD after 7, 13, 36, 42 and 70 days. respectively(4); these results indicated that 2,6-xylidine was not readily biodegradable according to OECD criteria, however, it is biodegradable after extended adaptation(4). In another OECD Guideline 301F study, 2,6-xylidine (at 100 mg/L) showed no bidegradation after 33 day(4). Using OECD Guideline 302B (Inherent biodegradability: Zahn-Wellens/EMPA Test) and an industrial activated sludge seed, 83% of initial 2,6-xylidine was removed from the aqueous test system after 11 days, however, the substance was mainly removed via volatilization(4). 2,6-Xylidine, present at 100 mg/L, reached 0% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(5).
An estimated BCF value of 8 was calculated for 2,6-xylidine in fish(SRC), using a log Kow of 1.84(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF value suggests that bioconcentration in aquatic organisms is low(SRC).
Using a structure estimation method based on molecular connectivity indices(1), the Koc of 2,6-xylidine can be estimated to be 190(SRC). According to a classification scheme(2), this estimated Koc value suggests that 2,6-xylidine is expected to have moderate mobility in soil. Aromatic amines are expected to bind strongly to humus or organic matter in soils due to the high reactivity of the aromatic amino group(3,4), suggesting that mobility may be lower in some soils(SRC). In a short term soil adsorption study using 14C-labelled 2,6-xylidine, 66% of the applied radioactivity was bound to the soil (3.4% organic matter, 36.6% sand, 28.2% silt, 35.2% clay) after 24 hrs(3).
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN3272 (For reference only, please check.)
IMDG: UN3272 (For reference only, please check.)
IATA: UN3272 (For reference only, please check.)
ADR/RID: ESTERS, N.O.S. (For reference only, please check.)
IMDG: ESTERS, N.O.S. (For reference only, please check.)
IATA: ESTERS, N.O.S. (For reference only, please check.)
ADR/RID: 3 (For reference only, please check.)
IMDG: 3 (For reference only, please check.)
IATA: 3 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
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The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.