中文名：氯（1-叔丁基茚基）鈀（II）二聚體
英文名：Chloro(1-t-butylindenyl)palladium(II) dimer
中文別名：Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200
英文別名：Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200
純度：98%
貨號(hào)：C282882
包裝：100mg、500mg
Cas號(hào)：1779569-01-5
存儲(chǔ)溫度：室溫
產(chǎn)品介紹：
Application
The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.
Product class
M-C, Homogeneous Catalysts, Hazari Catalyst, Indenyl Ligands
Reaction type
Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling Reaction
Chemical properties
Theoretical metal content
Applications & references
Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3.
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands.
Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)
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關(guān)鍵字： Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200;Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200
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