中文名:(S)-4-叔丁基-2-[2-(二苯基膦基)苯基]-2-噁唑啉
英文名:(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline
中文別名:(4S)-叔丁基-2-[2-(二苯基膦基)苯基]-4,5-二氫噁唑
英文別名:148461-16-9|(S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole|(S)-4-TERT-BUTYL-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-2-OXAZOLINE|(S)-4-tert-Butyl-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole|[2-[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol
純度:97%
貨號:I167399
包裝:100mg、500mg、250mg
Cas號:148461-16-9
存儲溫度:-20°C儲存,充氬
產品介紹:
The product is a phosphinooxazoline (PHOX) ligand introduced by Pfaltz and coworkers. These non-symmetrical modular P,N-ligands are particularly useful in cases where double bond migration leads to undesired products or mixtures of isomers.(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline can be used as a ligand for enantioselective Heck reaction without any C=C double bond migration byproduct. It can also be used in a rhodium(I)-catalyzed enantioselective desymmetrization reaction of meso-3,5-dimethyl glutaric anhydride, to form substituted syn-deoxypolypropionate fragments in a single transformation.
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關鍵字: (4S)-叔丁基-2-[2-(二苯基膦基)苯基]-4,5-二氫噁唑;148461-16-9;(S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole;(S)-4-TERT-BUTYL-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-2-OXAZOLINE
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