應(yīng)用
8-Isopropylquinoline N-oxide can be used as a reagent: In the oxidative cyclization of diynes in the presence of gold catalyst. For the preparation of pyrrolo[3,4-c]quinolin-1-ones by asymmetric alkyne oxidation of chiral N-propargyl ynamides in the presence of a copper catalyst. In the synthesis of 8-(1-methylethyl)-2-[(4-methylphenyl)sulfonyl]- quinoline by deoxygenative and selective sulfonylation with sodium p-toluenesulfinate using iodine/TBHP as a catalyst.
Sigma-Aldrich西格瑪奧德里奇(上海)貿(mào)易有限公司
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