一般描述
2,4,6-Cycloheptatriene-1-carbonitrile (7-Cyanocycloheptatriene) is a 7-substituted cycloheptatriene. Its synthesis by reacting tropylium cation with cyanide anion has been described. 2,4,6-cycloheptatriene-1-carbonitrile affords toluene or toluonitrile during flash photolysis studies. Its diamagnetic susceptibility has been determined, which is useful for the derivation of its susceptibility exaltation. It reacts with acetyl acetone in the presence of Mn(OAc)3 to form products derived from the norcaradiene structure.
應(yīng)用
用于環(huán)庚三烯自由基和陰離子的 EPR 和分子內(nèi)質(zhì)子轉(zhuǎn)移研究的有效模型。還可用于生成 dihydroazocines 和 hydrooxocins。
Sigma-Aldrich西格瑪奧德里奇(上海)貿(mào)易有限公司
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