3-氨基吡啶(462-08-8)核磁圖(13CNMR)
InChI:InChI=1S/C5H6N2/c6-5-2-1-3-7-4-5/h1-4H,6H2
InChIKey: CUYKNJBYIJFRCU-UHFFFAOYSA-N
Smiles:C1=NC=CC=C1N
-
Mass
MS-NW-2299
3-pyridylamine
C5H6N2 (Mass of molecular ion: 94)
Source Temperature: 260 °C
Sample Temperature: 170 °C
Reservoir, 75 eV
26.0 1.1
28.0 7.6
37.0 3.2
38.0 6.6
39.0 17.5
40.0 8.7
41.0 26.1
42.0 1.9
46.5 1.0
50.0 1.7
51.0 2.2
52.0 2.4
54.0 2.4
64.0 1.4
65.0 2.6
66.0 9.5
67.0 35.1
68.0 3.8
93.0 11.4
94.0 100.0
95.0 6.4
parameter in DMSO-d6
90 MHz in CDCl3
-
| 1H NMR |
300 MHz |
| C5 H6 N2
|
30 % in DMSO
|
| 3-pyridylamine
|
 |
Parameter ppm Hz
D(A) 8.53
D(B) 7.26
D(C) 7.40
D(D) 8.23
J(A,B) 1.5
J(A,C) 1.5
J(A,D) 0.0
J(B,C) 7.9
J(B,D) 3.2
J(C,D) 2.8
D(E) 5.80
BRUEGEL,W. Z.ELEKTROCHEM.(BER.BUNSENGES.PHYS.CHEM.)
66, 159 (1962)
|
Hz ppm Int.
2560.47 8.535 154
2559.04 8.530 275
2557.56 8.525 155
2472.01 8.240 130
2469.02 8.230 224
2466.03 8.220 136
2226.46 7.422 60
2224.95 7.416 66
2223.68 7.412 66
2222.17 7.407 61
2218.56 7.395 88
2217.05 7.390 95
2215.77 7.386 94
2214.29 7.381 84
2183.92 7.280 86
2182.44 7.275 91
2180.73 7.269 90
2179.24 7.264 85
2176.02 7.253 62
2174.54 7.248 64
2172.82 7.243 62
2171.34 7.238 58
1740.01 5.800 1000
-
| 1H NMR |
89.56 MHz |
| C5 H6 N2
|
0.049 g : 0.5 ml CDCl3
|
| 3-pyridylamine
|
|
Assign. Shift(ppm)
A 8.08
B 7.99
C 7.030
D 6.966
E 3.89
|
Hz ppm Int.
725.00 8.096 431
723.94 8.084 542
722.31 8.066 406
721.44 8.056 488
718.94 8.028 394
717.13 8.008 337
714.69 7.981 498
712.88 7.960 437
638.81 7.133 155
637.81 7.122 200
634.63 7.087 81
633.50 7.074 116
630.63 7.042 705
629.63 7.031 675
626.63 6.997 1000
625.31 6.983 767
624.69 6.976 811
624.06 6.969 718
622.25 6.948 680
618.50 6.906 154
616.56 6.885 102
615.88 6.877 182
614.06 6.857 123
347.81 3.884 426