橡膠防老劑 4010NA(101-72-4)質(zhì)譜(MS)

產(chǎn)品名稱:橡膠防老劑 4010NA

CAS:101-72-4

分子式:C15H18N2

分子量: 226.32

InChI:InChI=1S/C15H18N2/c1-12(2)16-14-8-10-15(11-9-14)17-13-6-4-3-5-7-13/h3-12,16-17H,1-2H3

InChIKey: OUBMGJOQLXMSNT-UHFFFAOYSA-N

Smiles:C1(NC(C)C)=CC=C(NC2=CC=CC=C2)C=C1

Mass

MS-IW-6346          
n-isopropyl-N'-phenyl-p-phenylenediamine
C15H18N2            (Mass of molecular ion:    226)

   Source Temperature: 140 °C
   Sample Temperature: 110 °C
   Direct, 75 eV

      51.0       1.6
      65.0       1.5
      77.0       3.5
      80.0       1.0
      91.0       1.7
      92.0       1.6
      93.0       1.1
     104.0       1.0
     104.5       1.0
     105.0       3.4
     105.5       9.1
     106.0       2.0
     107.0       1.2
     113.0       1.0
     117.0       1.3
     118.0       4.7
     119.0       3.9
     128.0       1.6
     129.0       1.4
     139.0       1.0
     154.0       1.5
     156.0       1.1
     166.0       3.3
     167.0       8.5
     168.0       5.3
     169.0       8.8
     170.0       1.2
     181.0       1.8
     182.0       3.6
     183.0      26.6
     184.0       6.5
     195.0       1.4
     209.0       2.9
     210.0       2.9
     211.0     100.0
     212.0      15.9
     213.0       1.3
     224.0       2.7
     225.0       6.2
     226.0      86.0
     227.0      15.0
     228.0       1.2

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₅ H₁₈ N₂	0.038 g : 0.5 ml CDCl₃
N-isopropyl-N'-phenyl-p-phenylenediamine

    Assign.     Shift(ppm)

      A             7.163
      B             6.983
      C             6.815
      D             6.758
      E             6.560
      F     *1      5.36
      G             3.579
      J     *1      3.3
      K             1.199

     Hz     ppm     Int.

   2871.46   7.185    111
   2869.38   7.180     37
   2864.14   7.167    151
   2862.92   7.164    154
   2857.54   7.151     46
   2855.59   7.146    139
   2795.78   6.996    233
   2793.58   6.991     72
   2789.18   6.980     76
   2786.87   6.974    257
   2783.69   6.966     30
   2728.64   6.828    137
   2727.54   6.825    180
   2726.68   6.823     92
   2725.46   6.820     48
   2721.92   6.811     46
   2720.95   6.809     82
   2719.85   6.806    153
   2718.87   6.804    137
   2709.11   6.779     40
   2708.01   6.776     61
   2706.91   6.774     32
   2701.90   6.761     58
   2700.68   6.758    106
   2699.71   6.756     50
   2694.46   6.743     33
   2693.36   6.740     51
   2626.22   6.572    238
   2624.02   6.566     71
   2619.63   6.555     68
   2617.43   6.550    219
   1437.13   3.596     59
   1430.91   3.581     80
   1424.56   3.565     61
    482.54   1.208    982
    476.20   1.192   1000

in CDCl3