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CAS No. : | 99-20-7 | MDL No. : | MFCD00006628 |
Formula : | C12H22O11 | Boiling Point : | - |
Linear Structure Formula : | C5H5O(OH)3(CH2OH)(OC5H5O(OH)3(CH2OH)) | InChI Key : | HDTRYLNUVZCQOY-LIZSDCNHSA-N |
M.W : | 342.30 | Pubchem ID : | 7427 |
Synonyms : |
D-Trehalose;α,α-Trehalose;NSC 2093;Trehalose;D-(+)-Trehalose
|
Chemical Name : | (2R,2'R,3S,3'S,4S,4'S,5R,5'R,6R,6'R)-6,6'-Oxybis(2-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol) |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P280-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
42% | With Amberlyst 15; In N,N-dimethyl-formamide; benzene; for 48h;Reflux; | General procedure: Trehalose acetals were synthesized based on a method previouslydescribed for the synthesis of 4,6,4',6'-di-O-(4-allyloxybenzylidene)-alpha,alpha-D-trehalose with some modifications[40]. The acetalization reaction was carried out using a two-neckround-bottom flask equipped with a DeaneStark trap, thermometerand reflux condenser. 30 mL of anhydrous benzene, 3.2 mL of2-, 3- or 4-allyloxybenzaldehyde and 1.13 g of Amberlyst 15 wereadded to a solution of 2.7 g (7.9 mmol) of dried trehalose in 15 mL of anhydrous DMF. The reaction was carried under reflux for 48 h.After this time, the catalyst was filtered off and benzene wasremoved under reduced pressure. A solution of the product in N,N-dimethylformamide(DMF) was treated several times with aqueous NaHCO3 and deionized water. The precipitate was washed threetimes with diethyl ether (30 mL) in order to remove x-allyloxybenzaldehyde.White powder was dried under a vacuum for 24 h. |