[ CAS No. 95753-55-2 ] {[proInfo.proName]}

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Quality Control of [ 95753-55-2 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 95753-55-2 ]

Product Details of [ 95753-55-2 ]

CAS No. :	95753-55-2	MDL No. :	MFCD00057810
Formula :	C₂₄H₂₀N₂O₆	Boiling Point :	-
Linear Structure Formula :	C₁₅H₁₁O₂NHCH(CH₂C₆H₄NO₂)COOH	InChI Key :	RZRRJPNDKJOLHI-QFIPXVFZSA-N
M.W :	432.43	Pubchem ID :	7016054
Synonyms :

Safety of [ 95753-55-2 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 95753-55-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 95753-55-2 ]

[ 95753-55-2 ] Synthesis Path-Downstream 1~10

1
[ 28920-43-6 ]
[ 949-99-5 ]
[ 95753-55-2 ]

Reference： [1]Journal of the Chemical Society. Perkin transactions II,1984,p. 1723 - 1728
[2]Bioorganic and Medicinal Chemistry Letters,1997,vol. 7,p. 715 - 718

2
[ 20866-48-2 ]
[ 71989-14-5 ]
[ 95753-55-2 ]
(R)-N₅-(tert.-butoxy-carbonyl)-N₂-(9-fluorenylmethoxycarbonyl)-ornithine [ No CAS ]
[ 106327-79-1 ]

Reference： [1]Journal of Medicinal Chemistry,1987,vol. 30,p. 2094 - 2099

3
[ 95753-55-2 ]
[ 95753-56-3 ]

Reference： [1]Bioorganic and Medicinal Chemistry Letters,1997,vol. 7,p. 715 - 718
[2]Journal of the Chemical Society. Perkin transactions II,1984,p. 1723 - 1728
[3]Tetrahedron Letters,1999,vol. 40,p. 6557 - 6560
[4]Journal of Medicinal Chemistry,2013,vol. 56,p. 1262 - 1275
[5]Russian Journal of Organic Chemistry,2016,vol. 52,p. 1681 - 1685
Zh. Org. Khim.,2016,vol. 52,p. 1686 - 1690,5

4
[ 949-99-5 ]
[ 82911-69-1 ]
[ 95753-55-2 ]

Yield	Reaction Conditions	Operation in experiment
67%	With sodium hydroxide; In water; acetonitrile; at 20℃; for 3h;	A solution of 80 mL of acetonitrile was added to a suspension of 37.7 g (0.179 mol) of acid 2a and 2b in 200 mL of 2% NaOH aqueous solution until complete dissolution. A solution of 61.8 g (0.183 mol) of suspension of Fmoc-OSu in 100 mL of acetonitrile was added to this solution. The reaction mixture was stirred for 3 hours at room temperature and acidified with 5% HCl to pH 4-5. The precipitated white crystals were filtered off, washed with ethyl acetate, and dried. The reaction product was recrystallized from ethanol-dioxane mixture, 50 : 50. Yield 67% (3a), 71% (3b). mp 230C (mp 233-234C [10]). IR spectrum nu, cm-1: 3429, 3202, 1724, 1693, 1601, 1520, 1447, 1354, 1223, 1057, 856, 760, 741. 1 NMR spectrum (DMSO-d6), delta, ppm: 2.90-3.09 m (1H, CH2), 3.25 d.d (1H, CH2, 2J 13.7, 3J 4.3 Hz), 4.13-4.34 m (4H, 2CH2, 2CH), 7.23-7.45 m (4Harom), 7.54 d (2Harom, 3J 8.6 Hz), 7.60-7.64 m (2Harom), 7.79 d (1H, NH, 3J 8.6 Hz), 7.88 d (2Harom, 3J 7.5 Hz ), 8.14 d (2Harom, 3J 8.6 Hz ), 12.93 s (1H, COOH). 13 NMR spectrum (DMSO-d6), delta, ppm: 36.62 (CH2), 47.03 (CH), 55.25 (CH), 66.03 (CH2), 120.56, 123.69, 125.62, 127.45, 128.07, 130.94, 141.16, 144.20, 146.73 (arom), 156.39 (CONH), 173.27 (COOH). Mass spectrum (ESI), m/z: 455.1214 [M + Na]+. C24H20N2O6. Calculated M 432.1321.

Reference： [1]Tetrahedron Letters,1999,vol. 40,p. 6557 - 6560
[2]Russian Journal of Organic Chemistry,2016,vol. 52,p. 1681 - 1685
Zh. Org. Khim.,2016,vol. 52,p. 1686 - 1690,5

5
[ 98946-18-0 ]
[ 95753-55-2 ]
[ 381222-37-3 ]

Reference： [1]Journal of Medicinal Chemistry,2001,vol. 44,p. 36 - 46

6
[ 112883-29-1 ]
[ 135248-89-4 ]
[ 95753-55-2 ]
[ 35737-15-6 ]
H₂N-4-NO₂-Phe-c[Cys-Tyr-D-Trp-Lys-Val-Cys]-Tyr-NH₂ [ No CAS ]

Reference： [1]Molecular Pharmacology,1996,vol. 50,p. 709 - 715

7
[ 105047-45-8 ]
[ 95753-55-2 ]
[ 35737-15-6 ]
[ 157355-80-1 ]
JF-04-27 [ No CAS ]

Reference： [1]Molecular Pharmacology,1996,vol. 50,p. 709 - 715

8
[ 123639-61-2 ]
[ 95753-55-2 ]
Fmoc-γ-cyclohexyl-L-glutamate [ No CAS ]
Fmoc-L-1-pyrenylalanine [ No CAS ]
Fmoc-pyrAla-Glu(OChx)-ntrPhe-Glu(OBzl)4-NH₂ [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2001,vol. 105,p. 10407 - 10415

9
[ 123639-61-2 ]
[ 95753-55-2 ]
Fmoc-γ-cyclohexyl-L-glutamate [ No CAS ]
Fmoc-L-1-pyrenylalanine [ No CAS ]
Fmoc-pyrAla-Glu(OChx)2-ntrPhe-Glu(OBzl)4-NH₂ [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2001,vol. 105,p. 10407 - 10415

10
[ 123639-61-2 ]
[ 95753-55-2 ]
Fmoc-γ-cyclohexyl-L-glutamate [ No CAS ]
Fmoc-L-1-pyrenylalanine [ No CAS ]
Fmoc-pyrAla-Glu(OChx)3-ntrPhe-Glu(OBzl)4-NH₂ [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2001,vol. 105,p. 10407 - 10415

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Isomers

Technical Information

? Acyl Group Substitution ? Arndt-Eistert Homologation ? Bouveault-Blanc Reduction ? Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions ? Catalytic Hydrogenation ? Chan-Lam Coupling Reaction ? Complex Metal Hydride Reductions ? Ester Cleavage ? Hunsdiecker-Borodin Reaction ? Hydride Reductions ? Leuckart-Wallach Reaction ? Mannich Reaction ? Passerini Reaction ? Petasis Reaction ? Preparation of Amines ? Preparation of Carboxylic Acids ? Reactions of Amines ? Reactions of Carboxylic Acids ? Reactions with Organometallic Reagents ? Schmidt Reaction ? Specialized Acylation Reagents-Carbodiimides and Related Reagents ? Specialized Acylation Reagents-Ketenes ? Specialized Acylation Reagents-Vilsmeier Reagent ? Ugi Reaction

Historical Records

Related Functional Groups of
[ 95753-55-2 ]

Amino Acid Derivatives

[ 177966-63-1 ]

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[ 117402-88-7 ]

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[ 61280-75-9 ]

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[ CAS No. 95753-55-2 ] {[proInfo.proName]}

Quality Control of [ 95753-55-2 ]

Related Doc. of [ 95753-55-2 ]

Product Details of [ 95753-55-2 ]

Safety of [ 95753-55-2 ]

Application In Synthesis of [ 95753-55-2 ]

[ 95753-55-2 ] Synthesis Path-Downstream 1~10

Technical Information

Related Functional Groups of [ 95753-55-2 ]

Amino Acid Derivatives

Precautionary Statements-General

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[ 95753-55-2 ]