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CAS No. : | 948592-54-9 | MDL No. : | MFCD16877431 |
Formula : | C12H16BClO3 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | MTZMRMZJCYVKSJ-UHFFFAOYSA-N |
M.W : | 254.52 | Pubchem ID : | 53486836 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362-P403+P233-P501 | UN#: | |
Hazard Statements: | H302-H312-H332 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With potassium carbonate; In N,N-dimethyl acetamide; at 100℃; for 10h; | Methanesulfonic acid 2-methoxyethyl ester (70.5 mg, 0.50 mmol) and 2-[2-chloro-5- hydroxyphenyl]-4,4,5,5-tetramethyl-[1 ,3,2]-dioxaborolane (Preparation 66, 100 mg, 0.42 mmol) were stirred together in N,N-dimethylacetamide (4 ml). Potassium carbonate (58 mg, 0.42 mmol) was added and the resultant solution was heated to 1000C for 10 hours. The reaction mixture was cooled then quenched with water (10 ml) and extracted with ethylacetate (10 ml).The organic layer was dried over anhydrous MgSO4 (s), filtered and evaporated in vacuo Xo give crude title compound. Material taken on without further purification. |
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