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CAS No. : | 93-08-3 | MDL No. : | MFCD00004108 |
Formula : | C12H10O | Boiling Point : | No data available |
Linear Structure Formula : | (C10H7)C(O)CH3 | InChI Key : | XSAYZAUNJMRRIR-UHFFFAOYSA-N |
M.W : | 170.21 | Pubchem ID : | 7122 |
Synonyms : |
|
Chemical Name : | 1-(Naphthalen-2-yl)ethanone |
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With sodium hydroxide; In ethanol; water; at 20℃; for 2h; | General procedure: An aqueous solution of sodium hydroxide (5%, 10mL) was added slowly to the stirring solution of isatin (1mmol) and appropriate aryl acetophenone (1mmol) in ethanol (20mL) in 100mL conical flask. The stirring was continued for 2h and the completion of reaction was monitored by TLC. The reaction on completion was poured onto ice, solid obtained after filtration was crystallized from ethanol. The physical data for the characteristic compound is shown below: |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With sodium hydroxide; In methanol; water; at 20℃; for 16h; | 2-Acetylnaphthalene (511 mg, 3.0 mmol) was dissolved in MeOH (10 mL) and <strong>[32024-15-0]3-iodo-4,5-dimethoxybenzaldehyde</strong> (876 mg, 3.0 mmol) was added. 5% NaOH (3.0 mL) was added and the reaction mixture was stirred at room temperature for 16 h. The formed precipitate was collected, washed with MeOH and dried in vacuum. Yield: 1.127 g (2.54 mmol, 85%); |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
The 1,1,3-triphenyl-2-methylacetylene-1-alcohol (152 mg, 1.0 mmol), cat. [Au] (6 mg, 1 μM %), AgOTf (2.6 mg, 1 μM %), water (36 mg, 2 mmol) and methanol (1 ml) are added to the 25 mL of Claisen tube or. After closing the reaction at 120 C for 6 hours, cooling to room temperature. Then adding formic acid amine (315 mg, 5 mmol) and cat. [Rh] (6.2 mg, 1 mmol %), the reaction mixture in oil bath heated to 80 C, reaction 12 hours, cooling to room temperature. Rotary evaporation of the solvent and add a certain amount of ethyl acetate and water extraction, the organic phase of the resulting product after concentrated hydrochloric acid the reflux process, rotary evaporation to remove the solvent, the final petroleum ether washing and filtering to obtain the pure target compound, yield: 84% |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
61% | With sodium hydroxide; In dimethyl sulfoxide; at 20℃; | General procedure: To a solution of 3,3-bis(methylsulfanyl)methylenemalononitrile 1 (1.70 g, 10 mmol) in 20 mL of DMSO, keton 2a - j (10 mmol) and powdered sodium hydroxide (0.8 20 mmol) were added, and the mixture was magnetically stirred for 4 - 5 h at room temperature. After addition of 300 mL of water to the mixture, the solution was stirred for 12 h at room temperature. The formed precipitate was collected by filtra- tion and washed several times with water. After drying under air, the formed product was recrystallized using methanol or ethanol to obtain the pure products. |
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1-([1,1'-Biphenyl]-4-yl)ethanone
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