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[ CAS No. 92511-12-1 ] {[proInfo.proName]}

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Chemical Structure| 92511-12-1
Chemical Structure| 92511-12-1
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Product Details of [ 92511-12-1 ]

CAS No. :92511-12-1 MDL No. :MFCD01863695
Formula : C10H23IOSi Boiling Point : -
Linear Structure Formula :- InChI Key :INGJYKISFRSCQV-UHFFFAOYSA-N
M.W : 314.28 Pubchem ID :4250746
Synonyms :
Chemical Name :tert-Butyl(4-iodobutoxy)dimethylsilane

Safety of [ 92511-12-1 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P280-P305+P351+P338 UN#:N/A
Hazard Statements:H302 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 92511-12-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 92511-12-1 ]

[ 92511-12-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 161609-84-3 ]
  • [ 92511-12-1 ]
  • [ 959689-83-9 ]
YieldReaction ConditionsOperation in experiment
67% With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - 20℃; for 18.5h; Benzyl 4-(4-(tert-butyldimethylsilyloxy)butyl)-4-cyanopiperidine-1-carboxylate. To a stirred solution of <strong>[161609-84-3]benzyl 4-cyanopiperidine-1-carboxylate</strong> (10 g, 410 mmol) and iodo-tert-butyldimethylsilane butane (12.6 mL, 49 mmol) in THF (80 mL) cooled to -78 C. was added LiHMDS (50 mL, 50 mmol, 1M in THF) dropwise over 30 min. The resulting mixture was stirred while gradually warming to room temperature for 18 h. After quenching with water, the organic phase was diluted with EtOAc and washed with water, brine and dried (Na2SO4). After concentration, the residue was purified by flash chromatography (1% to 20% EtOAc/hexane) to give the title compound as yellow oil (11.88 g, 67% yield). 1H NMR (300 MHz, CDCl3) delta: 7.34-7.28 (5H, m), 5.09 (2H, s), 4.17 (2H, bs), 3.59 (2H, t, J=5.3 Hz), 3.07 (2H, bs), 1.89 (2H, d, J=13.2 Hz), 1.53 (6H, bs), 1.43-1.34 (2H, m), 0.85 (9H, s), 0.01 (6H, s). LCMS (M+H): 431.20.
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[ 92511-12-1 ]

Iodides

Chemical Structure| 78878-05-4

[ 78878-05-4 ]

tert-Butyl(3-iodopropoxy)dimethylsilane

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