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CAS No. : | 89-78-1 | MDL No. : | MFCD00062983 |
Formula : | C10H20O | Boiling Point : | - |
Linear Structure Formula : | (HO)C6H9(CH3)CH(CH3)2 | InChI Key : | - |
M.W : | 156.27 | Pubchem ID : | - |
Synonyms : |
Racementhol;(±)-Menthol;CCRIS 375;NSC 2603
|
Chemical Name : | rel-(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P273-P301+P312+P330-P302+P352-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335-H413 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
61% | With rhodium(III) chloride trihydrate; copper diacetate; In N,N-dimethyl-formamide; at 90℃; under 760.051 Torr; for 10h;Sealed tube; | AddN-pyrimidinylpurine 1a (0.2 mmol), RhCl3?3H2O (0.004 mmol), Cu(OAc)2(0.4 mmol) and2-isopropyl-5-methylcyclohexanol 2r (1.0 mmol) to 2.0 mL DMF, in a Young tube setafter the change of carbon monoxide three times, charged with carbon monoxide (1 atm), the reaction and after 90 deg.] C oil bath for 10 hours, the reaction was stopped, to be antisolution was cooled to room temperature, ethyl acetate and saturated The saline is washed and extracted several times.The organic phase was dried over anhydrous sodium sulfateand filtered.The solvent was evaporated to dryness, and ethyl acetate / petroleum ether (1:10to 1:1).The product was a white solid with a yield of 61%. |