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CAS No. : | 79887-09-5 | MDL No. : | MFCD00173885 |
Formula : | C12H14 | Boiling Point : | - |
Linear Structure Formula : | C4H9C6H4CCH | InChI Key : | ZVWWYEHVIRMJIE-UHFFFAOYSA-N |
M.W : | 158.24 | Pubchem ID : | 2775132 |
Synonyms : |
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Chemical Name : | 4-Butylphenylacetylene |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P264-P271-P280-P302+P352-P304+P340+P312-P305+P351+P338-P332+P313-P337+P313-P403+P233-P405-P501 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 20℃; for 2h; | First, 65 g (209 mmol) of <strong>[175278-30-5]1-iodo-2-ethyl-4-bromobenzene</strong> and 38 g (226 mmol) of 4-n-butylphenylacetylene were introduced into 300 ml of NEt3, 1 g (5.3 mmol) of copper (I) iodide 3.6 g (5.1 mmol) bis (triphenylphosphine) palladium (II) chloride, and the mixture was stirred at room temperature for 2 hours. The batch was cooled, water and heptane were added, and the phases were separated. The organic phase is washed with saturated sodium chloride solution, dried over sodium sulfate, filtered and evaporated on a rotary evaporator. The residue was purified by column chromatography (SiO2, heptane); the product was obtained as a colorless oil. |