There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | ||||||
{[ item.p_purity ]} | {[ item.pr_size ]} | Inquiry |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,1,item.pr_is_large_size_no_price) ]} |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate,item.pr_is_large_size_no_price) ]} | {[ item.pr_usastock ]} | in stock Inquiry - | {[ item.pr_chinastock ]} | {[ item.pr_remark ]} in stock Inquiry - | Login | Inquiry |
Please Login or Create an Account to: See VIP prices and availability
CAS No. : | 776-75-0 | MDL No. : | MFCD00023702 |
Formula : | C12H15NO | Boiling Point : | - |
Linear Structure Formula : | C6H4CONC4H8CH3 | InChI Key : | YXTROGRGRSPWKL-UHFFFAOYSA-N |
M.W : | 189.25 | Pubchem ID : | 69892 |
Synonyms : |
|
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P264-P270-P280-P301+P312-P305+P351+P338-P310-P330-P501 | UN#: | 1760 |
Hazard Statements: | H302-H318 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
84% | General procedure: In a nitrogen-filled glovebox, to a 15 mL reaction tube equipped with a magnetic stirrer, were added Cp2ZrH2 (0.01mmol, 2.2 mg) as the catalyst, and the appropriate amide (0.2mmol); solvent was added when necessary. HBpin (3 equiv. peramide functional group) was then added, and the reaction tube was taken out from the glovebox and stirred at room temperature for 12-48 h. The resultant crude amines were either isolated using silica gel flash chromatography, or acidified by stirring with HCl in Et2O (2 mL, 1N) for 2 h, after which time precipitation was observed. Then, the reaction solution was transferred to a centrifuge tube and centrifuged three times. The supernatant was removed and the resulting solid was dried inan oven at 80 C for several hours to obtain the HCl salt of the amine. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86%Spectr.; 13%Spectr. | With 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; In neat (no solvent); at 120℃; for 24h;Inert atmosphere; Sealed tube; | General procedure: N,N-dimethylbenzamide (0.0746 g,0.5 mmol), or N-methylbenzamide (0.0676 g, 0.5 mmol) was taken in culture tube (11 ml) at 25 C, sealed with septum, the air in culture tube was replaced with argon gas. After adding pinacolborane (0.36 ml, 2.5 mmol 5 equiv), the screw cap was closed, stirred at 120 C for 24 h. Afterthis time, it was cooled to room temperature, excess HBpin was quenched by adding water (0.1 ml). After adding 2 ml of 5 N NaOH (aq), reaction mixture was extracted with ether (20 ml). The organic part was dried over MgSO4, filtered and dried under high vacuum to remove volatile organic impurities. The yield was analyzed by 1HNMR (using acetonitrile [8μl, 0.33 eq] as an internal standard). |
[ 292635-34-8 ]
(4-(Aminomethyl)phenyl)(piperidin-1-yl)methanone
Similarity: 1.00
[ 923120-30-3 ]
4-[(Azepan-1-yl)carbonyl]benzylamine
Similarity: 0.98
[ 93300-61-9 ]
N-(12-Benzamidododecyl)-N-methylbenzamide
Similarity: 0.98
[ 878440-79-0 ]
[4,4'-Bipiperidin]-1-yl(phenyl)methanone
Similarity: 0.95
[ 926259-94-1 ]
(4-Aminopiperidin-1-yl)(p-tolyl)methanone
Similarity: 0.95
[ 292635-34-8 ]
(4-(Aminomethyl)phenyl)(piperidin-1-yl)methanone
Similarity: 1.00
[ 923120-30-3 ]
4-[(Azepan-1-yl)carbonyl]benzylamine
Similarity: 0.98
[ 93300-61-9 ]
N-(12-Benzamidododecyl)-N-methylbenzamide
Similarity: 0.98
[ 878440-79-0 ]
[4,4'-Bipiperidin]-1-yl(phenyl)methanone
Similarity: 0.95
[ 926259-94-1 ]
(4-Aminopiperidin-1-yl)(p-tolyl)methanone
Similarity: 0.95
[ 292635-34-8 ]
(4-(Aminomethyl)phenyl)(piperidin-1-yl)methanone
Similarity: 1.00
[ 851322-39-9 ]
Phenyl(3,9-diazaspiro[5.5]undecan-3-yl)methanone
Similarity: 0.95
[ 878440-79-0 ]
[4,4'-Bipiperidin]-1-yl(phenyl)methanone
Similarity: 0.95
[ 926259-94-1 ]
(4-Aminopiperidin-1-yl)(p-tolyl)methanone
Similarity: 0.95
[ 150514-60-6 ]
(4-Aminopiperidin-1-yl)(phenyl)methanone
Similarity: 0.95