Alternatived Products of [ 7699-41-4 ]
Product Details of [ 7699-41-4 ]
CAS No. : | 7699-41-4 |
MDL No. : | MFCD00054122 |
Formula : |
H2O3Si
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | IJKVHSBPTUYDLN-UHFFFAOYSA-N |
M.W : |
78.10
|
Pubchem ID : | 14768 |
Synonyms : |
|
Safety of [ 7699-41-4 ]
Signal Word: | Warning |
Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 |
UN#: | N/A |
Hazard Statements: | H319-H335 |
Packing Group: | N/A |
GHS Pictogram: |
|
Application In Synthesis of [ 7699-41-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 7699-41-4 ]
- 1
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[ 6802-75-1 ]
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[ 37688-96-3 ]
-
[ 7699-41-4 ]
-
[ 103199-02-6 ]
Yield | Reaction Conditions | Operation in experiment |
86% |
copper(l) chloride; In tetrahydrofuran; petrol ether; benzene; |
EXAMPLE 20 1,1,18,18-tetra(carboethoxy)-2,2,17,17-tetramethyloctadecane The procedure of Example 1 was followed except that the bis-Grignard reagent was prepared from 3.0 g of <strong>[37688-96-3]1,14-dibromotetradecane</strong> and 0.75 g of Mg turnings in 40 ml of dry THF. The bis-Grignard reagent was then added dropwise to a stirred suspension of 0.031 g CuCl and 3.72 g of diethyl isopropylidenemalonate in 15 ml of dry THF. The addition product was protonated and extracted into ether as in Example 1 followed by silicic acid (400 mesh) chromatography in benzene:petrol ether 1:2.5 to yield the title compound. 86% yield. NMR (CDCl3): 4.3 (q, 8H); 3.5 (s, 2H); 1.5 (m, 40H); 1.1 (m, 12H). |