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CAS No. : | 75128-73-3 | MDL No. : | MFCD00267706 |
Formula : | C12H15N5O5 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | VBHLKZHSCMQLTI-UHFFFAOYSA-N |
M.W : | 309.28 | Pubchem ID : | 135433881 |
Synonyms : |
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Chemical Name : | 2-((2-Acetamido-6-oxo-1H-purin-9(6H)-yl)methoxy)ethyl acetate |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
94.3% | With toluene-4-sulfonic acid; In toluene; at 110℃;Large scale; | (1) Add 2700L of anhydrous toluene, 600 kg of diacetylguanine and 15 kg of p-toluenesulfonic acid to the reaction kettle, and heat to reflux.(2) Maintain the temperature at 110 C, add 675L of 2-oxa-1,4-butanediol diacetate, and control the addition for 1 hour.(3) Insulation reflux for about 1 hour.(4) Maintain the reflux reaction, and slowly rectify toluene under normal pressure within 16 hours. The toluene distillation rate is 90 L / h, and 1440 L of toluene is co-distilled.(5) After evaporating toluene for 6 hours, start to add about 900L of anhydrous toluene at a rate of 90L / h.(6) After the reaction was completed, the temperature was lowered to below 30 C and centrifuged, and the obtained solid was dried at 105 C to obtain 744.0 kg of diacetyl acyclovir with a yield of 94.3% and a HPLC detection content of 99.2%. |