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CAS No. : | 69555-14-2 | MDL No. : | MFCD00010590 |
Formula : | C17H17NO2 | Boiling Point : | No data available |
Linear Structure Formula : | (C6H5)2CNCH2C(O)OC2H5 | InChI Key : | QUGJYNGNUBHTNS-UHFFFAOYSA-N |
M.W : | 267.32 | Pubchem ID : | 319508 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With diisopropylamine; | Step B 2-[(N-Diphenylmethylene)amino]-3-(4-bromo-3-pyridinyl) propanoic acid, ethyl ester To a solution of N-(diphenylmethylene)glycine ethyl ester (4.30 g, 16.11 mmol) in TEE (25 mL) at -78 C. was added dropwise a 2.0M solution of LDA in TEE (8.0 mL, 16.0 mmol). After being stirred for 30 min at -78 C., a solution of 2-bromo-5-bromomethyl-pyridine in 10 mL of TEE was added and the reaction allowed to warm to rt. After 1 h, the reaction was diluted with EtOAc (50 mL) and washed with water (50 mL) and saturated aqueous NaCl (50 mL). The organic layer was dried over anhydrous MgSO4 and concentrated in vacuo to give a yellow oil. The oil was purified by flash column chromatography on silica gel eluted with hexane/EtOAc (10:1) to yield 2-[(N-diphenylmethylene)amino]-3-(4-bromo-3-pyridinyl) propanoic acid, ethyl ester as a pale yellow oil. |
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