[ CAS No. 6939-93-1 ] {[proInfo.proName]}

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2D 3D

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Quality Control of [ 6939-93-1 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 6939-93-1 ]

SDS Specification

Alternatived Products of [ 6939-93-1 ]

Product Details of [ 6939-93-1 ]

CAS No. :	6939-93-1	MDL No. :	MFCD00002404
Formula :	C₈H₅BrO₄	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	MSQIEZXCNYUWHN-UHFFFAOYSA-N
M.W :	245.03	Pubchem ID :	81361
Synonyms :

Safety of [ 6939-93-1 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 6939-93-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 6939-93-1 ]

[ 6939-93-1 ] Synthesis Path-Downstream 1~5

1
[ 887757-25-7 ]
[ 6939-93-1 ]

Reference： [1]Chemische Berichte,1891,vol. 24,p. 3768

2
[ 2840-29-1 ]
[ 6939-93-1 ]

Reference： [1]Chemische Berichte,1891,vol. 24,p. 3768

3
[ 6939-93-1 ]
[ 63746-12-3 ]

Reference： [1]European Journal of Medicinal Chemistry,2011,vol. 46,p. 2880 - 2894

4
[ 2645-22-9 ]
copper(II) acetate tetrahydrate [ No CAS ]
[ 6939-93-1 ]
[Co(dps)(Brip)]_n [ No CAS ]

Reference： [1]Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry,2013,vol. 43,p. 892 - 896

5
[ 67-56-1 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 143131-66-2 ]
[ 6939-93-1 ]
Cd⁽²⁺⁾*C₈H₃BrO₄^(2-)*2H₂O*0.5C₁₂H₁₂N₆*0.5CH₄O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	In water; at 150℃; for 72h;Autoclave;	Cd(NO3)·4H2O (0.063g, 0.2mmol), 4-Br-H2ip (0.025g, 0.1mmol), btx (0.024g, 0.1mmol), methanol (1mL) and H2O (4mL) were mixed and stirred at room temperature for 30min. Those mixtures were sealed in the Teflon-lined autoclave and heated at 150C for 3 days. Colorless block-like crystals 3 were obtained with 75% yield based on Cd. Anal. Calcd for C29H30Br2N6O13Cd2: C, 33.00; H, 2.87; N, 7.96; Found: C, 33.22; H, 2.82; N, 8.11; IR (solid KBr pellet, cm-1) of 7: 3437 (m), 3131 (w), 1696 (w), 1596 (w), 1525 (m), 1388 (s), 1317 (s), 1272 (m), 1210 (w), 1129 (m), 1021 (w), 975 (w), 885 (w), 768 (w), 731 (w), 669 (m), 630 (w), 505 (w).

Reference： [1]Journal of Solid State Chemistry,2016,vol. 244,p. 12 - 19

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Technical Information

? Alkyl Halide Occurrence ? Arndt-Eistert Homologation ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Friedel-Crafts Reaction ? General Reactivity ? Grignard Reaction ? Hiyama Cross-Coupling Reaction ? Hunsdiecker-Borodin Reaction ? Hydrogenolysis of Benzyl Ether ? Kinetics of Alkyl Halides ? Kumada Cross-Coupling Reaction ? Passerini Reaction ? Preparation of Alkylbenzene ? Preparation of Amines ? Preparation of Carboxylic Acids ? Reactions of Alkyl Halides with Reducing Metals ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reactions of Carboxylic Acids ? Reactions of Dihalides ? Schmidt Reaction ? Specialized Acylation Reagents-Ketenes ? Stille Coupling ? Substitution and Elimination Reactions of Alkyl Halides ? Suzuki Coupling ? Ugi Reaction ? Vilsmeier-Haack Reaction

Historical Records

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[ 6939-93-1 ]

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P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
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P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
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P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
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H400	Very toxic to aquatic life
H401	Toxic to aquatic life
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H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
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H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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[ CAS No. 6939-93-1 ] {[proInfo.proName]}

Quality Control of [ 6939-93-1 ]

Related Doc. of [ 6939-93-1 ]

Product Details of [ 6939-93-1 ]

Safety of [ 6939-93-1 ]

Application In Synthesis of [ 6939-93-1 ]

[ 6939-93-1 ] Synthesis Path-Downstream 1~5

Technical Information

Related Functional Groups of [ 6939-93-1 ]

Aryls

Bromides

Carboxylic Acids

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 6939-93-1 ]