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CAS No. : | 693-23-2 | MDL No. : | MFCD00002735 |
Formula : | C12H22O4 | Boiling Point : | - |
Linear Structure Formula : | (CH2)10(COOH)2 | InChI Key : | TVIDDXQYHWJXFK-UHFFFAOYSA-N |
M.W : | 230.30 | Pubchem ID : | 12736 |
Synonyms : |
|
Chemical Name : | Dodecanedioic acid |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H319 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
31% | With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In N,N-dimethyl-formamide; at 0℃; | Synthesis of2-(1 -(2-nitrophenyl)ethoxy)-1 2-oxododecanoic acid10480] Dodecanedioic acid (6 g, 26.1 mmol), cat. DMAP, and 1-2(-nitrophenyl)ethanol (1.45 g, 8.7 mmol) were dissolved in DMF (70 mE), and the solution was cooled to 0° C. To the mixture was added 1 -Ethyl-3-(3-dimethylaminopro- pyl)carbodiimide (EDCI) (2.5 g, 13 mmol) and the reaction was stirred overnight and warmed to room temperature. The solution was taken up into EtOAc (500 mE) and washed with water, iN HC1, and sat. NH4C1 solutions. The organic layer was dried over Na2504. The volatiles were evaporated and the residue was purified on silica gel chromatography (gradient hexanes:EtOAc, 5:1 to 4:1 to 3:1 to 2:1), affording 2-(1- (2-nitrophenyl)ethoxy)-12-oxododecanoic acid as a thick oil in 31percent yield. 1H NMR (300 MHz, CDC13): oe=1.21 (br.s, 12H), 1.49-1.66 (m, 7H), 2.20-2.33 (m, 4H), 6.27 (q, 1H, J=6 Hz), 7.30-7.43 (m, 1H), 7.53-7.65 (m, 2H), 7.87 (d, 1H, J=8.2 Hz). 13C NMR (300 Hz, CDC13): oe=20.8, 21.9, 24.6, 24.7, 28.7, 29.0, 29.1, 29.3, 34.0, 34.2, 67.8, 124.3, 127.1, 128.3,133.5, 138.0, 147.7, 172.7, 177.6, 180.3. |
A1340064[ 1173019-20-9 ]
dodecanedioic-1,2,3,4,5,6,7,8,9,10,11,12-13C12 acid
Reason: Stable Isotope