[ CAS No. 67385-09-5 ] {[proInfo.proName]}

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2D 3D

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Quality Control of [ 67385-09-5 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 67385-09-5 ]

SDS Specification

Alternatived Products of [ 67385-09-5 ]

Product Details of [ 67385-09-5 ]

CAS No. :	67385-09-5	MDL No. :	MFCD00274335
Formula :	C₇H₁₅NO₂S	Boiling Point :	-
Linear Structure Formula :	(CH₃)₃COOCNHCH₂CH₂SH	InChI Key :	GSJJCZSHYJNRPN-UHFFFAOYSA-N
M.W :	177.26	Pubchem ID :	3017761
Synonyms :		Chemical Name :	tert-Butyl (2-mercaptoethyl)carbamate

Safety of [ 67385-09-5 ]

Signal Word:	Danger	Class:	9
Precautionary Statements:	P260-P264-P270-P273-P280-P301+P312+P330-P304+P312-P305+P351+P338-P314-P337+P313-P391-P501	UN#:	3082
Hazard Statements:	H302-H319-H332-H372-H400	Packing Group:	Ⅲ
GHS Pictogram:

Application In Synthesis of [ 67385-09-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 67385-09-5 ]

[ 67385-09-5 ] Synthesis Path-Downstream 1~3

1
[ 178747-50-7 ]
[ 67385-09-5 ]
[ 178747-51-8 ]

Yield	Reaction Conditions	Operation in experiment
80%	With potassium carbonate; In N-methyl-acetamide;	(b) 3-(2-(N-t-Butoxycarbonylamino)ethylthio)-5-fluoro-1,2-benzisoxazole. To a solution of <strong>[178747-50-7]3-chloro-5-fluoro-1,2-benzisoxazole</strong> (0.83 g) in dimethylformamide (8 ml) was added 2-t-butoxycarbonylaminoethanethiol (0.86 g) and potassium carbonate (0.67 g) with stirring under nitrogen atmosphere, and the mixture was then stirred at 80 C. for 3 hours. The reaction mixture was poured into ice water, extracted with ethyl acetate and the combined extracts were washed with brine and dried over anhydrous magnesium sulphate. After filtration, the solvent was evaporated under reduced pressure and the residue was purified by silica gel column chromatography, to give the title compound (1.21 g, 80%) as a colorless powder. NMR spectrum(CDCl3)deltappm: 1.44(9H,s), 3.41(2H,t,J=6.2 Hz), 3.58(2H,td,J=6.2 Hz,J=6.2 Hz), 4.98(1H,brs), 7.21-7.51(3H,m).

Reference： [1]Patent: US5965591,1999,A

2
[ 67385-09-5 ]
[ 82632-80-2 ]
[ 1333307-92-8 ]

Reference： [1]Angewandte Chemie - International Edition,2011,vol. 50,p. 7865 - 7869

3
[ 67385-09-5 ]
[ 69655-76-1 ]
[ 1588948-20-2 ]

Reference： [1]Chemical Science,2014,vol. 5,p. 1046 - 1053

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Isomers

Technical Information

? Acyl Group Substitution ? Bouveault-Blanc Reduction ? Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions ? Catalytic Hydrogenation ? Chan-Lam Coupling Reaction ? Complex Metal Hydride Reductions ? Ester Cleavage ? Heat of Combustion ? Hydride Reductions ? Lawesson's Reagent ? Leuckart-Wallach Reaction ? Mannich Reaction ? Oxidation States of Sulfur Compounds ? Petasis Reaction ? Preparation of Amines ? Reactions of Amines ? Reactions with Organometallic Reagents ? Specialized Acylation Reagents-Carbodiimides and Related Reagents ? Specialized Acylation Reagents-Ketenes ? Specialized Acylation Reagents-Vilsmeier Reagent ? Ugi Reaction

Historical Records

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[ 67385-09-5 ]

Aliphatic Chain Hydrocarbons

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P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
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P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
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P401
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P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
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P501	Dispose of contents/container to ...
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Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
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H205	May mass explode in fire
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H240	Heating may cause an explosion
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H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
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H260	In contact with water releases flammable gases which may ignite spontaneously
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H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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[ CAS No. 67385-09-5 ] {[proInfo.proName]}

Quality Control of [ 67385-09-5 ]

Related Doc. of [ 67385-09-5 ]

Product Details of [ 67385-09-5 ]

Safety of [ 67385-09-5 ]

Application In Synthesis of [ 67385-09-5 ]

[ 67385-09-5 ] Synthesis Path-Downstream 1~3

Technical Information

Related Functional Groups of [ 67385-09-5 ]

Aliphatic Chain Hydrocarbons

Amides

Amines

Thiols

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 67385-09-5 ]