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CAS No. : | 64085-52-5 | MDL No. : | MFCD09753734 |
Formula : | C6H5BrIN | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | KISIGYZVSJKAEK-UHFFFAOYSA-N |
M.W : | 297.92 | Pubchem ID : | 13803667 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
71% | CuO (1 g, 12.6 mmol) was added to a stirred solution of 5-bromo-2-iodo-aniline (2.5 g, 8.30mmol) and tert-butyl N-(2-amino-2-thioxo-ethyl)carbamate (2 g, 10.9 mmol) in DMF (15 mL)at RT and the reaction mixture was purged with argon for 15 mm. Then dppf (929 mg, 1.60mmol) and Pd2(dba)3 (768 mg, 0.8 mmol) were added to the reaction mixture and degassedwith argon for further 5 mm. The reaction mixture was stirred in a sealed tube at 70°C for 4 h and filtered through celite pad which was washed with EtOAc (50 mL). The filtrate was washed with water (2x30 mL) and concentrated under reduced pressure. The crude compound was purified by flash chromatography eluting with 20percent EtOAc in petroleum ether affording an offwhite solid (2 g, 7 1percent). M/z 343.0 (M+H). |
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