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CAS No. : | 5981-09-9 | MDL No. : | MFCD00778301 |
Formula : | C18H18N4 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | SNLFYGIUTYKKOE-UHFFFAOYSA-N |
M.W : | 290.36 | Pubchem ID : | 80083 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
71% | With triethylamine; In acetonitrile; at 20℃; for 24h;Inert atmosphere; | 2.00 g (1 .9 mmol) 2-chloi -l ,3-dimethyl-4J5-dihydro-lH-imidazol-3-ium chloride (II) in 20 mL acetonitrile were added, to a suspension of 1.00 g (3.4 mmol) Nl ,Nl-bis(4- aminophenyl)benzene-l ,4-diamine in 30 mL acetonitrile and 3.8 mL tri ethyl amine under argon atmosphere. The mixture was stirred for 24 hours at room temperature. After distillation of the solvent, the residue was suspended in 2 M sodium hydroxide solution and stirred for 5 minutes at 45 °C. 1.4 g (2.42 mmol; 71 percent) rose solid were obtained after filtration, washing with water and acetone and drying in vacuo. The product was purified by gradient sublimation for analytical characterisation. Melting point: 226 °C |
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