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CAS No. : | 58556-75-5 | MDL No. : | MFCD00238580 |
Formula : | C10H6Br2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | ODJZWBLNJKNOJK-UHFFFAOYSA-N |
M.W : | 285.96 | Pubchem ID : | 625355 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
75% | With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; sodium hydroxide; In water; toluene; at 80℃; for 12h;Inert atmosphere; | Under a nitrogen atmosphere, (27.2 g, 100 mmol) of compound 11-6-1 and (28.4 g, 100 mmol) of compound 9-2-1, (6.9 g, 6 mmol) Tetrakis (triphenylphosphonium) palladium, (5.2g, 16mmol) tetrabutylammonium bromide, (4g, 100mmol) sodium hydroxide, (50mL) water and (300mL) toluene were added to a 500mL three-necked flask and heated at 80 C The reaction was stirred for 12 hours. The reaction was completed. Most of the solvent was removed by rotary evaporation, washed with dichloromethane and washed with water 3 times, and the organic liquid was collected and purified by silica gel column. The yield was 75%. |
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