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CAS No. : | 580-19-8 | MDL No. : | MFCD01646243 |
Formula : | C9H8N2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | RZAUIOKDXQWSQE-UHFFFAOYSA-N |
M.W : | 144.17 | Pubchem ID : | 11377 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P280-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H332-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 20℃; for 0.5h; | Commercially available B5.1 (1.02 g, 5.86 mmol) was dissolved in -30 mL DMF with 1.5 mL DIEA. To this stirring solution was added 850 mg (5.86 mmol, 1 eq) of 7- aminoquinoline. The reaction was stirred at room temperature for 30 minutes. An aliquot (~.5 mmol) was taken aside, and to it was added 0.1 mL DIEA and H-D-Val-NH2 HCl. This reaction mixture was stirred for 3 hours at 50°C and then cooled. Water and DCM was added and the layers were separated. The organic layer was washed with 10percent NaHC03 and was concentrated. Crude B5.2 was dissolved in -10 mL MeOH. To this solution, -50 mg K2C03 and -1 mL H202 (40percent by wt) were added. The reaction was stirred at 50°C for 30 minutes and then was concentrated. The crude was purified by rpHPLC to give the title compound. MS found for C19H21N702 as (M+H)+380.2. |
[ 1187931-81-2 ]
1-Quinolin-5-yl-methylamine hydrochloride
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