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CAS No. : | 5545-17-5 | MDL No. : | MFCD00152053 |
Formula : | C10H16N2O6S2 | Boiling Point : | - |
Linear Structure Formula : | (CH3CONHCH(CH2S)COOH)2 | InChI Key : | YTPQSLLEROSACP-YUMQZZPRSA-N |
M.W : | 324.37 | Pubchem ID : | 6995101 |
Synonyms : |
DiNAC;(Ac-Cys-OH)2;N,N-Diacetylcystine;D-7193;D-7042;NSC 203780;N,N’-Diacetylcystine
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With cis-diaammineplatinum(IV) tetrachloride; In aq. acetate buffer; at 25℃;pH 4.51;Kinetics; | General procedure: An Applied Photophysics SX-20 stopped-flow spectrometer( Applied Photophysics Ltd., Leatherhead, U.K.) was employed for kinetic measurements; the kinetic traces were simulated by the software provided by Applied Photophysics. Stock solutions ofNAC(20-30 mM) were prepared just before the kinetic measurements by dissolving a certain amount NAC in buffers; the stock solutions were flushed with nitrogen for 10 min and were only used for a couple of hours. Solutions of NAC and of the Pt(IV) complexes for kinetic measurements were prepared, respectively, by adding an appropriate amount of the Pt(IV) stock solution and NAC to a specific buffer. Those solutions were flushed for10 min with nitrogen before loading onto the stopped-flow machine. Reactions were started by mixing equal volumes of NACand platinum(IV) solutions directly in the stopped-flow machine. Pseudo first-order conditions were fulfilled by keeping NAC in at least ten fold excess. | |
With mefenamic Acid; In aq. phosphate buffer; ethanol; water;Electrolysis; | General procedure: A mixture of a phosphate buffer (ca. 50 ml; c = 0.2 M,pH = 7.0) in water/ethanol (30:70 v/v) solution, containing mefenamic acid (1) (0.02 mmol) and glutathione (0.3 mmol) (3) orN-acetyl-L-cysteine (3?) was electrolyzed in a divided cell at 0.6 Vvs Ag/AgCl. The electrolysis was terminated when the currentdecreased by more than 95%. After having finished the electrolysis,the precipitated solid was collected by filtration and washed severaltimes with water. The products were characterized by infraredspectroscopy,7 mass spectroscopy, and melting point measurements. |