Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | ||||||
{[ item.p_purity ]} | {[ item.pr_size ]} | Inquiry |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,1,item.pr_is_large_size_no_price) ]} |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate,item.pr_is_large_size_no_price) ]} | {[ item.pr_usastock ]} | in stock Inquiry - | {[ item.pr_chinastock ]} | {[ item.pr_remark ]} in stock Inquiry - | Login | Inquiry |
Please Login or Create an Account to: See VIP prices and availability
CAS No. : | 536-57-2 | MDL No. : | MFCD00058979 |
Formula : | C7H8O2S | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | FXJVNINSOKCNJP-UHFFFAOYSA-N |
M.W : | 156.20 | Pubchem ID : | 10818 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P280-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H332-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
82% | With copper; isopentyl nitrite; In acetonitrile; at 0 - 25℃; for 12h;Schlenk technique; Inert atmosphere; | General procedure: Arylamine (1) (0.5 mmol),Cu powder (1.5 mmol, 96 mg), arylsulfinic acid (2) (1.5 mmol) and acetonitrile (1 mL)were added to a dry Schlenk tube equipped with a magnetic stir bar, and then isoamylnitrite (1.5 mmol, 175.5 mg) in 1 mL of acetonitrile was injected slowly into the tubeat 0 oC under nitrogen atmosphere. After a 1 h stirring at this temperature, the tubewas kept at room temperature for 11-23 h under nitrogen atmosphere. The resultingsolution was concentrated by a rotary evaporator, and the residue was purified bycolumn chromatography on silica gel to provide the desired product (3a-u). |