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CAS No. : | 51673-84-8 | MDL No. : | MFCD00134410 |
Formula : | C4H8O3 | Boiling Point : | - |
Linear Structure Formula : | CHOCH(OCH3)2 | InChI Key : | OGFKTAMJLKHRAZ-UHFFFAOYSA-N |
M.W : | 104.10 | Pubchem ID : | 162650 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
71% | General procedure: To a solution of compound 8 (150 mg, 1.17 mmol) in dry CH2Cl2 (10 ml) at -35 C were added a solution of TiCl4 (0.19 ml, 1.75 mmol) and tributylamine (0.83 ml, 3.5 mmol) in CH2Cl2 (2 ml each). After stirring the resulting solution for 30 minutes at same temperature, 1 ml solution of 2,2-dimethoxy acetaldehye (5.85 mmol) in CH2Cl2 (extracted from 60% aqueous solution) was added and the reaction mixture was allowed to attain room temperature. Once the reaction was complete (confirmed by TLC), water (15 ml) was added to quench the reaction. Workup was done with CH2Cl2 (3 x 15 ml) and after washing the organic portion with brine (25 ml), it was dried over sodium sulphate (2 g). Solvent was removed under reduced pressure and the resulting crude reaction mixture was subjected to column chromatography with ethyl acetate/hexane (3:97). The product was obtained as a colorless liquid in 67% yield (104 mg). |
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