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CAS No. : | 4389-50-8 | MDL No. : | MFCD00007809 |
Formula : | C8H9NO2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | XHYVBIXKORFHFM-UHFFFAOYSA-N |
M.W : | 151.16 | Pubchem ID : | 151210 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | palladium; | REFERENCE EXAMPLE 17 2-Amino-6-methylbenzoic acid To a methanolic solution (150 ml) of <strong>[13506-76-8]6-methyl-2-nitrobenzoic acid</strong> (14.25 g) was added palladium-on-carbon (1.40 g) and the hydrogenation reaction was conducted at atmospheric temperature and pressure (hydrogen consumption 5.3 1). The catalyst was filtered off and the filtrate was concentrated under reduced pressure to provide the title compound as light-yellow solid (15.12 g; yield 100%). 1 H-NMR (CDCl3) δ: 2.47(3H,s), 6.50(2H,t,J=8.1Hz), 7.00-7.07(4H,m). IR (KBr): 2927, 2645, 1645, 1599, 1545, 1470, 1394, 1334, 1288, 1236, 813, 775, 580, 419 cm-1. |
1.2 g | With palladium on activated charcoal; hydrogen; In methanol; at 20℃; for 2h; | Pd/C (150 mg) was added to a solution of <strong>[13506-76-8]2-methyl-6-nitrobenzoic acid</strong> (1.5 g, 8.29 mmol) inCHOH (35 ml). The mixture was stirred at room temperature under H2 atmosphere for 2h.Then the mixture was filtered and concentrated to afford 1.2 g of the title compound as yellow solid. LCMS (ESI): calc’d for C8H9N02 [M+H]: 152, found: 152. |
With 2 % platinum on carbon; hydrogen; In methanol; at 70 - 80℃; under 7500.75 - 9750.98 Torr;Autoclave; | 2-Methyl-6-nitrobenzoic acid (500 g), platinum carbon (platinum content: 2%, 50 g), methanol (2000 g), put them into the autoclave, replace with nitrogen, and let the hydrogen pressure be 1.0-1.3 MPa, increase the temperature to 70-80C, control the temperature and control the reaction pressure until the reaction is complete (raw material |
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